Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes

Global energy demand is met in large part, by burning of fossil fuels, which is causing global warming. Mixed matrix membranes (MMMs) with metal organic frameworks (MOFs) as fillers are an interesting alternative for capturing post combustion CO2 which would make the energy sector sustainable. This...

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Autores: Hasan, Md. Rafiul, Paseta, Lorena, Malankowska, Magdalena, Téllez, Carlos, Coronas, Joaquín
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/280732
Acceso en línea:http://hdl.handle.net/10261/280732
Access Level:acceso abierto
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spelling Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranesHasan, Md. RafiulPaseta, LorenaMalankowska, MagdalenaTéllez, CarlosCoronas, JoaquínGlobal energy demand is met in large part, by burning of fossil fuels, which is causing global warming. Mixed matrix membranes (MMMs) with metal organic frameworks (MOFs) as fillers are an interesting alternative for capturing post combustion CO2 which would make the energy sector sustainable. This research is focused on the synthesis of MOF ZIF-94 from the recycling of its mother liquors and the incorporation of synthesized MOF into a Pebax MH 1657 for MMM fabrication. The pH and the temperature of ZIF-94 synthesis are modified and monitored and this results in various nanoparticle diameters (average particle size in the range of 41 ± 8–180 ± 73 nm). Incorporation of ZIF-94 significantly improves the performance of the bare Pebax MH 1657 membrane. The maximum CO2/N2 selectivity and CO2 permeability are obtained for 10 wt% ZIF-94 loading in 9 wt% (polymer concentration in 70/30 (v/v) ethanol/water solution) Pebax MH 1657 matrix being 36 ± 7 (71% increment compared to bare membrane) and 137 ± 31 Barrer (80% improvement), respectively.This project received funding from the European Union Horizon 2020 research and innovation program under Grant Agreement No. 760944 (MEMBER project). Grant PID2019-104009RB-I00 funded by MCIN/AEI/10.13039/501100011033 (Agencia Estatal de Investigación, Spain) and Grant T43-20R (the Aragón Government) are gratefully acknowledged.Peer reviewedWiley-VCHEuropean CommissionGobierno de AragónMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/280732reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/760944info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104009RB-I00The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1002/adsu.202100317https://doi.org/10.1002/adsu.202100317Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2807322026-05-22T06:33:51Z
dc.title.none.fl_str_mv Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
title Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
spellingShingle Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
Hasan, Md. Rafiul
title_short Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
title_full Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
title_fullStr Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
title_full_unstemmed Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
title_sort Synthesis of ZIF-94 from recycled mother liquors: Study of the influence of its loading on postcombustion CO2 capture with pebax based mixed matrix membranes
dc.creator.none.fl_str_mv Hasan, Md. Rafiul
Paseta, Lorena
Malankowska, Magdalena
Téllez, Carlos
Coronas, Joaquín
author Hasan, Md. Rafiul
author_facet Hasan, Md. Rafiul
Paseta, Lorena
Malankowska, Magdalena
Téllez, Carlos
Coronas, Joaquín
author_role author
author2 Paseta, Lorena
Malankowska, Magdalena
Téllez, Carlos
Coronas, Joaquín
author2_role author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Gobierno de Aragón
Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description Global energy demand is met in large part, by burning of fossil fuels, which is causing global warming. Mixed matrix membranes (MMMs) with metal organic frameworks (MOFs) as fillers are an interesting alternative for capturing post combustion CO2 which would make the energy sector sustainable. This research is focused on the synthesis of MOF ZIF-94 from the recycling of its mother liquors and the incorporation of synthesized MOF into a Pebax MH 1657 for MMM fabrication. The pH and the temperature of ZIF-94 synthesis are modified and monitored and this results in various nanoparticle diameters (average particle size in the range of 41 ± 8–180 ± 73 nm). Incorporation of ZIF-94 significantly improves the performance of the bare Pebax MH 1657 membrane. The maximum CO2/N2 selectivity and CO2 permeability are obtained for 10 wt% ZIF-94 loading in 9 wt% (polymer concentration in 70/30 (v/v) ethanol/water solution) Pebax MH 1657 matrix being 36 ± 7 (71% increment compared to bare membrane) and 137 ± 31 Barrer (80% improvement), respectively.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/280732
url http://hdl.handle.net/10261/280732
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/760944
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104009RB-I00
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1002/adsu.202100317
https://doi.org/10.1002/adsu.202100317
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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