Toxicity of seabird guano to sea urchin embryos and interaction with Cu and Pb

Guano is an important source of marine-derived nutrients to seabird nesting areas. Seabirds usually present high levels of metals and other contaminantsbecause the bioaccumulation processes and biotic depositions can increase the concentration of pollutantsin the receiving environments. The objectiv...

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Detalhes bibliográficos
Autores: Rial, Diego, Santos-Echeandía, Juan, Álvarez-Salgado, Xosé Antón, Jordi, Antoni, Tovar-Sánchez, Antonio, Bellas, Juan
Formato: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2016
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/321347
Acesso em linha:http://hdl.handle.net/10261/321347
Access Level:acceso abierto
Palavra-chave:Centro Oceanográfico de Vigo
Antagonism
Medio Marino
Joint toxicity
Response surface
Sea urchin embryo
Seabird guano
Trace metals
Descrição
Resumo:Guano is an important source of marine-derived nutrients to seabird nesting areas. Seabirds usually present high levels of metals and other contaminantsbecause the bioaccumulation processes and biotic depositions can increase the concentration of pollutantsin the receiving environments. The objectives of this study were to investigate: the toxicity of seabird guano and the joint toxicity of guano, Cu and Pb by using the sea urchin embryo-larval bioassay. In a first experiment, aqueous extracts of guano were prepared at two loading rates (0.462 and 1.952 g L-1) and toxicity to sea-urchin embryos was tested. Toxicity was low and not dependent of the load of guano used (EC50: 0.42±0.03 g L-1). Trace metal concentrations were also low either in guano or in aqueous extracts of guano and the toxicity of extracts were apparently related to dissolved organic matter. In a second experiment, the toxicity of Cu-Pb mixtures in artificial seawater and in extracts of guano (at two loadings: 0.015 and 0.073 g L-1), was tested. According to individual fittings, Cu added to extracts of guano showed less toxicity than when dissolved in artificial seawater. The response surfaces obtained for mixtures of Cu and Pb in artificial seawater, and in 0.015 g L-1 and 0.073 g L-1 of guano, were better described by Independent Action model adapted to describe antagonism, than by the other proposed models, according to the Akaike Information Criterion. This implied accepting that EC50 for Cu and Pb increased with the load of guano and with a greater interaction for Cu than for Pb.