Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications

Space cooling and heating, ventilation, and air conditioning (HVAC) accounts for roughly 10% of global electricity use and are responsible for ca. 1.13 gigatonnes of CO emissions annually. Adsorbent-based HVAC technologies have long been touted as an energy-efficient alternative to traditional refri...

Descripción completa

Detalles Bibliográficos
Autores: Camur, Ceren|||0000-0002-4475-0511, Babu, Robin, Suárez del Pino, Jose Antonio|||0000-0001-5469-8959, Rampal, Nakul, Pérez-Carvajal, Javier|||0000-0002-6916-1158, Hügenell, Philipp, Ernst, Sebastian-Johannes, Silvestre-Albero, Joaquin|||0000-0002-0303-0817, Imaz, Inhar|||0000-0002-0278-1141, Madden, David G., Maspoch Comamala, Daniel|||0000-0003-1325-9161, Fairen-Jimenez, David|||0000-0002-5013-1194
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:287086
Acceso en línea:https://ddd.uab.cat/record/287086
https://dx.doi.org/urn:doi:10.1002/adma.202209104
Access Level:acceso abierto
id ES_82771e1d0e9eb9fe4868c2f046fc5f7e
oai_identifier_str oai:ddd.uab.cat:287086
network_acronym_str ES
network_name_str España
repository_id_str
spelling Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption ApplicationsCamur, Ceren|||0000-0002-4475-0511Babu, RobinSuárez del Pino, Jose Antonio|||0000-0001-5469-8959Rampal, NakulPérez-Carvajal, Javier|||0000-0002-6916-1158Hügenell, PhilippErnst, Sebastian-JohannesSilvestre-Albero, Joaquin|||0000-0002-0303-0817Imaz, Inhar|||0000-0002-0278-1141Madden, David G.Maspoch Comamala, Daniel|||0000-0003-1325-9161Fairen-Jimenez, David|||0000-0002-5013-1194Space cooling and heating, ventilation, and air conditioning (HVAC) accounts for roughly 10% of global electricity use and are responsible for ca. 1.13 gigatonnes of CO emissions annually. Adsorbent-based HVAC technologies have long been touted as an energy-efficient alternative to traditional refrigeration systems. However, thus far, no suitable adsorbents have been developed which overcome the drawbacks associated with traditional sorbent materials such as silica gels and zeolites. Metal-organic frameworks (MOFs) offer order-of-magnitude improvements in water adsorption and regeneration energy requirements. However, the deployment of MOFs in HVAC applications has been hampered by issues related to MOF powder processing. Herein, three high-density, shaped, monolithic MOFs (UiO-66, UiO-66-NH, and Zr-fumarate) with exceptional volumetric gas/vapor uptake are developed-solving previous issues in MOF-HVAC deployment. The monolithic structures across the mesoporous range are visualized using small-angle X-ray scattering and lattice-gas models, giving accurate predictions of adsorption characteristics of the monolithic materials. It is also demonstrated that a fragile MOF such as Zr-fumarate can be synthesized in monolithic form with a bulk density of 0.76 gcm without losing any adsorption performance, having a coefficient of performance (COP) of 0.71 with a low regeneration temperature (≤ 100 °C). 22023-01-0120232023-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/287086https://dx.doi.org/urn:doi:10.1002/adma.202209104reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2019-108453GB-C21European Commission https://doi.org/10.13039/501100000780 726380open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2870862026-06-06T12:50:31Z
dc.title.none.fl_str_mv Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
title Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
spellingShingle Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
Camur, Ceren|||0000-0002-4475-0511
title_short Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
title_full Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
title_fullStr Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
title_full_unstemmed Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
title_sort Monolithic Zirconium-Based Metal-Organic Frameworks for Energy-Efficient Water Adsorption Applications
dc.creator.none.fl_str_mv Camur, Ceren|||0000-0002-4475-0511
Babu, Robin
Suárez del Pino, Jose Antonio|||0000-0001-5469-8959
Rampal, Nakul
Pérez-Carvajal, Javier|||0000-0002-6916-1158
Hügenell, Philipp
Ernst, Sebastian-Johannes
Silvestre-Albero, Joaquin|||0000-0002-0303-0817
Imaz, Inhar|||0000-0002-0278-1141
Madden, David G.
Maspoch Comamala, Daniel|||0000-0003-1325-9161
Fairen-Jimenez, David|||0000-0002-5013-1194
author Camur, Ceren|||0000-0002-4475-0511
author_facet Camur, Ceren|||0000-0002-4475-0511
Babu, Robin
Suárez del Pino, Jose Antonio|||0000-0001-5469-8959
Rampal, Nakul
Pérez-Carvajal, Javier|||0000-0002-6916-1158
Hügenell, Philipp
Ernst, Sebastian-Johannes
Silvestre-Albero, Joaquin|||0000-0002-0303-0817
Imaz, Inhar|||0000-0002-0278-1141
Madden, David G.
Maspoch Comamala, Daniel|||0000-0003-1325-9161
Fairen-Jimenez, David|||0000-0002-5013-1194
author_role author
author2 Babu, Robin
Suárez del Pino, Jose Antonio|||0000-0001-5469-8959
Rampal, Nakul
Pérez-Carvajal, Javier|||0000-0002-6916-1158
Hügenell, Philipp
Ernst, Sebastian-Johannes
Silvestre-Albero, Joaquin|||0000-0002-0303-0817
Imaz, Inhar|||0000-0002-0278-1141
Madden, David G.
Maspoch Comamala, Daniel|||0000-0003-1325-9161
Fairen-Jimenez, David|||0000-0002-5013-1194
author2_role author
author
author
author
author
author
author
author
author
author
author
description Space cooling and heating, ventilation, and air conditioning (HVAC) accounts for roughly 10% of global electricity use and are responsible for ca. 1.13 gigatonnes of CO emissions annually. Adsorbent-based HVAC technologies have long been touted as an energy-efficient alternative to traditional refrigeration systems. However, thus far, no suitable adsorbents have been developed which overcome the drawbacks associated with traditional sorbent materials such as silica gels and zeolites. Metal-organic frameworks (MOFs) offer order-of-magnitude improvements in water adsorption and regeneration energy requirements. However, the deployment of MOFs in HVAC applications has been hampered by issues related to MOF powder processing. Herein, three high-density, shaped, monolithic MOFs (UiO-66, UiO-66-NH, and Zr-fumarate) with exceptional volumetric gas/vapor uptake are developed-solving previous issues in MOF-HVAC deployment. The monolithic structures across the mesoporous range are visualized using small-angle X-ray scattering and lattice-gas models, giving accurate predictions of adsorption characteristics of the monolithic materials. It is also demonstrated that a fragile MOF such as Zr-fumarate can be synthesized in monolithic form with a bulk density of 0.76 gcm without losing any adsorption performance, having a coefficient of performance (COP) of 0.71 with a low regeneration temperature (≤ 100 °C).
publishDate 2023
dc.date.none.fl_str_mv 2
2023-01-01
2023
2023-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/287086
https://dx.doi.org/urn:doi:10.1002/adma.202209104
url https://ddd.uab.cat/record/287086
https://dx.doi.org/urn:doi:10.1002/adma.202209104
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2019-108453GB-C21
European Commission https://doi.org/10.13039/501100000780 726380
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869412048314564608
score 15,198674

Similares en LA Referencia