Potential of ammonia as H2 carrier for dual-fuel combustion in CI engines

As the search for sustainable transportation fuels continues, ammonia emerges as a particularly promising candidate, especially for maritime applications where its toxicity is less of a concern. Being liquid at moderate pressures, ammonia offers advantages over hydrogen in terms of storage, handling...

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Bibliographic Details
Authors: Domínguez Pérez, Víctor Manuel, Gómez Doménech, Diego, Ramos Diezma, Ángel, Hernández Adrover, Juan José, Rodríguez Fernández, José
Format: article
Publication Date:2025
Country:España
Institution:Universidad Camilo José Cela (UCJC)
Repository:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/44565
Online Access:https://doi.org/10.1016/j.ijhydene.2025.151055
https://hdl.handle.net/10578/44565
Access Level:Open access
Keyword:Ammonia
Compression-ignition engines
Dual-fuel combustion
Hydrogen
Description
Summary:As the search for sustainable transportation fuels continues, ammonia emerges as a particularly promising candidate, especially for maritime applications where its toxicity is less of a concern. Being liquid at moderate pressures, ammonia offers advantages over hydrogen in terms of storage, handling, and energy density, making it a viable hydrogen carrier. This study examines a dual-fuel compression-ignition engine operating on diesel and ammonia at substitution ratios of 10–30 %. Despite adjustments to operating conditions, primarily EGR and combustion timing, ammonia resulted in lower thermal efficiency and increased NOx emissions compared to conventional combustion. Furthermore, the high N2O emissions led to an overall rise in CO2 equivalent emissions. However, when compared to hydrogen at the same substitution ratio, ammonia achieved higher thermal efficiency, likely due to reduced cylinder walls heat losses