Spinodal decomposition of Fe-Cu nanocrystals: Control of atomic-magnetic-moment and magnetic properties

Experimental results corresponding to the saturation magnetization and coercive field during the decomposition, upon annealing, of bcc and fcc Fe_xCu_(1-x), obtained by mechanical alloying are reported. The overall behavior points out that the decomposition takes place in two steps: (i) at low tempe...

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Detalles Bibliográficos
Autores: Crespo del Arco, Patricia, Hernando Grande, Antonio, Garcia Escorial, A.
Tipo de recurso: artículo
Fecha de publicación:1994
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/60120
Acceso en línea:https://hdl.handle.net/20.500.14352/60120
Access Level:acceso abierto
Palabra clave:538.9
Fexcu100-X solid-solutions
Immiscible elements
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:Experimental results corresponding to the saturation magnetization and coercive field during the decomposition, upon annealing, of bcc and fcc Fe_xCu_(1-x), obtained by mechanical alloying are reported. The overall behavior points out that the decomposition takes place in two steps: (i) at low temperatures a decrease of the saturation magnetic moment as well as an anomalous thermal dependence of coercive field are observed, however, no phase transformation is detected, and (ii) for further annealing temperatures a new phase appears; the magnetization tends to increase and the coercive field abruptly increases. The analysis of the results leads us to conclude that the first step corresponds to a spinodal decomposition. Fluctuations in the local composition give rise to coexistence of adjacent regions with Curie temperature varying continuously in a range of 1000 K across distances of a few nanometers, thus allowing the tailoring of the magnetic nanostructures.