Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties

The design of new systems with DonoreAcceptor properties is of great interest for the construction of optoelectronic new devices. Considering the strong supramolecular interaction of triazines with graphene a series of imine-derived triazines with DonoreAcceptor properties have been designed. These...

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Author: D. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. Ramírez
Format: article
Publication Date:2016
Country:España
Institution:Universidad de Castilla-La Mancha
Repository:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/38578
Online Access:https://hdl.handle.net/10578/38578
Access Level:Embargoed access
Keyword:Microwave, Green chemistry, Triazine, Donor-Acceptor, Imine
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spelling Synthesis of Imine-Derived Triazines with Donor-Acceptor PropertiesD. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. RamírezMicrowave, Green chemistry, Triazine, Donor-Acceptor, ImineThe design of new systems with DonoreAcceptor properties is of great interest for the construction of optoelectronic new devices. Considering the strong supramolecular interaction of triazines with graphene a series of imine-derived triazines with DonoreAcceptor properties have been designed. These compounds have been prepared in good to excellent yields (47e92%) using Green conditions, i.e. microwave irradiation in the absence of an acid catalyst. Their properties as DonoreAcceptor systems have been studied by Ultravioletevisible and fluorescence spectroscopy and by electrochemical studies. These imine derived triazines are blue-violet emitters (ca. 396 nm) and show large Stokes shifts (c.a. 6700 cm 1) and the electrochemical studies shows a high degree of communication between the acceptor triazines and the donor moieties (oxidation potentials up to 1.10 V). These characteristics makes them excellent candidates for the interaction with graphene and the construction of optoelectronic devices, as blue Light Emitting-Diodes (LEDs).202420242016info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10578/38578reponame:RUIdeRA. Repositorio Institucional de la UCLMinstname:Universidad de Castilla-La ManchaInglésElsevierinfo:eu-repo/semantics/embargoedAccessoai:ruidera.uclm.es:10578/385782026-05-27T07:36:41Z
dc.title.none.fl_str_mv Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
title Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
spellingShingle Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
D. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. Ramírez
Microwave, Green chemistry, Triazine, Donor-Acceptor, Imine
title_short Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
title_full Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
title_fullStr Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
title_full_unstemmed Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
title_sort Synthesis of Imine-Derived Triazines with Donor-Acceptor Properties
dc.creator.none.fl_str_mv D. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. Ramírez
author D. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. Ramírez
author_facet D. R. Corrochano, A. de la Hoz, A. M. Sánchez-Migallón,, R. Caballero, J. R. Ramírez
author_role author
dc.subject.none.fl_str_mv Microwave, Green chemistry, Triazine, Donor-Acceptor, Imine
topic Microwave, Green chemistry, Triazine, Donor-Acceptor, Imine
description The design of new systems with DonoreAcceptor properties is of great interest for the construction of optoelectronic new devices. Considering the strong supramolecular interaction of triazines with graphene a series of imine-derived triazines with DonoreAcceptor properties have been designed. These compounds have been prepared in good to excellent yields (47e92%) using Green conditions, i.e. microwave irradiation in the absence of an acid catalyst. Their properties as DonoreAcceptor systems have been studied by Ultravioletevisible and fluorescence spectroscopy and by electrochemical studies. These imine derived triazines are blue-violet emitters (ca. 396 nm) and show large Stokes shifts (c.a. 6700 cm 1) and the electrochemical studies shows a high degree of communication between the acceptor triazines and the donor moieties (oxidation potentials up to 1.10 V). These characteristics makes them excellent candidates for the interaction with graphene and the construction of optoelectronic devices, as blue Light Emitting-Diodes (LEDs).
publishDate 2016
dc.date.none.fl_str_mv 2016
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10578/38578
url https://hdl.handle.net/10578/38578
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Elsevier
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:RUIdeRA. Repositorio Institucional de la UCLM
instname:Universidad de Castilla-La Mancha
instname_str Universidad de Castilla-La Mancha
reponame_str RUIdeRA. Repositorio Institucional de la UCLM
collection RUIdeRA. Repositorio Institucional de la UCLM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812429

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