Supporting Information: Stereoselective, ruthenium-photocatalyzed synthesis of 1,2-diaminotruxinic bis-amino acids from 4-arylidene-5(4 H)-oxazolones
Figures for the Experimental Section (illustration of the setup utilized for in situ NMR experiments and continuous-flow reactions), control 1H NMR spectra of oxazolones 1, copies of 1H, 13C, and 19F NMR spectra for all new compounds 2 and 3, DP4 characterization of the μ-isomer, conversions (percen...
| Autores: | , , , , , , , , , |
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| Tipo de recurso: | conjunto de datos |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/330318 |
| Acceso en línea: | http://hdl.handle.net/10261/330318 |
| Access Level: | acceso abierto |
| Sumario: | Figures for the Experimental Section (illustration of the setup utilized for in situ NMR experiments and continuous-flow reactions), control 1H NMR spectra of oxazolones 1, copies of 1H, 13C, and 19F NMR spectra for all new compounds 2 and 3, DP4 characterization of the μ-isomer, conversions (percent) of oxazolones 1 to give cyclobutene-bis(oxazolones) 2 from two consecutive reactions in microreactors, copies of the absorption (UV–vis) spectra of (Z)-oxazolones 1 and selected (E)-oxazolones, quenching experiments, LFP experiments, cyclic voltammograms, and DFT calculations (optimized geometries and tables with absolute and relative energies) (PDF). Geometries: coordinates of all species calculated in Figure 11, using different functionals, basis and solvents (ZIP). |
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