2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols

A controlled access to 1-aryl 2,3-diiodo-carbazoles involving iodine transposition has been accomplished directly from acyclic precursors. The 2,3-diiodo-carbazole core was prone to further chemoselective decoration at C3−I or double difunctionalization. (Figure presented.).

Detalles Bibliográficos
Autores: Martín-Mejías, I., Petcu, Sonia A., Alonso, José M., Aragoncillo, Cristina, Almendros, Pedro
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/288902
Acceso en línea:http://hdl.handle.net/10261/288902
Access Level:acceso abierto
Palabra clave:carbazole
cascade reactions
cyclization
iodine translocation
Metal-free
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spelling 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynolsMartín-Mejías, I.Petcu, Sonia A.Alonso, José M.Aragoncillo, CristinaAlmendros, Pedrocarbazolecascade reactionscyclizationiodine translocationMetal-freeA controlled access to 1-aryl 2,3-diiodo-carbazoles involving iodine transposition has been accomplished directly from acyclic precursors. The 2,3-diiodo-carbazole core was prone to further chemoselective decoration at C3−I or double difunctionalization. (Figure presented.).This work was supported in part by MCIN/AEI /10.13039/501100011033/FEDER (Project PGC2018-095025-B-I00). I. M. thanks MCIN for a predoctoral contract. A. S. P. thanks CAM and FEDER (YEI) for a contractWiley-VCHMinisterio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)Comunidad de MadridEuropean CommissionConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2023202320222023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/288902reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-095025-B-I00http://dx.doi.org/10.1002/adsc.202200564Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2889022026-05-22T06:33:51Z
dc.title.none.fl_str_mv 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
title 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
spellingShingle 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
Martín-Mejías, I.
carbazole
cascade reactions
cyclization
iodine translocation
Metal-free
title_short 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
title_full 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
title_fullStr 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
title_full_unstemmed 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
title_sort 2,3-Diodocarbazoles by a Domino Iodocyclization/Iodo-Translocation of (3-Iodoindolyl)butynols
dc.creator.none.fl_str_mv Martín-Mejías, I.
Petcu, Sonia A.
Alonso, José M.
Aragoncillo, Cristina
Almendros, Pedro
author Martín-Mejías, I.
author_facet Martín-Mejías, I.
Petcu, Sonia A.
Alonso, José M.
Aragoncillo, Cristina
Almendros, Pedro
author_role author
author2 Petcu, Sonia A.
Alonso, José M.
Aragoncillo, Cristina
Almendros, Pedro
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Agencia Estatal de Investigación (España)
Comunidad de Madrid
European Commission
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv carbazole
cascade reactions
cyclization
iodine translocation
Metal-free
topic carbazole
cascade reactions
cyclization
iodine translocation
Metal-free
description A controlled access to 1-aryl 2,3-diiodo-carbazoles involving iodine transposition has been accomplished directly from acyclic precursors. The 2,3-diiodo-carbazole core was prone to further chemoselective decoration at C3−I or double difunctionalization. (Figure presented.).
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/288902
url http://hdl.handle.net/10261/288902
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-095025-B-I00
http://dx.doi.org/10.1002/adsc.202200564
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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