MAPLE synthesis of reduced graphene oxide/silver nanocomposite electrodes: Influence of target composition and gas ambience

Graphene oxide (GO) and reduced GO films with different amounts of silver nanoparticles (Ag NPs) have been deposited on quartz and silicon substrates by matrix assisted pulsed laser evaporation (MAPLE). The morphology, structure, chemical composition, and optical and electrochemical properties were...

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Detalles Bibliográficos
Autores: Queraltó, Albert, Pérez del Pino, Ángel, Logofatu, Constantin, Datcu, Angela, Amade, Roger, Alshaikh, Islam, Bertrán Serra, Enric, Urzica, Iuliana, Gyorgy, Eniko
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/155896
Acceso en línea:http://hdl.handle.net/10261/155896
Access Level:acceso abierto
Palabra clave:Graphene oxide nanocomposites
MAPLE
Graphene oxide-silver electrode
Energy storage
Descripción
Sumario:Graphene oxide (GO) and reduced GO films with different amounts of silver nanoparticles (Ag NPs) have been deposited on quartz and silicon substrates by matrix assisted pulsed laser evaporation (MAPLE). The morphology, structure, chemical composition, and optical and electrochemical properties were evaluated by scanning electron microscopy, X-ray photoelectron spectroscopy, ultraviolet–visible spectrophotometry, and cyclic voltammetry measurements. The properties of the films obtained with two types of GO precursors have been compared. A reduction of the amount of oxygen containing groups is observed with the increase of the Ag concentration, which leads to a decrease of the optical band gap. Moreover, the deposition in nitrogen gas ambience leads to the N-doping of rGO material. The films obtained with the highest amount of Ag and with nitrogen doping show potential to be used in energy storage electrodes.