Solvent-cast direct-writing as a fabrication strategy for radiopaque stents

Bioresorbable stents (BRS) potential in treating coronary heart disease is still to be further developed. Current trends include research with new polymeric materials, the need for thinner struts combined with appropriate mechanical properties, radiopacity and optimized local drug delivery. This wor...

Descripción completa

Detalles Bibliográficos
Autores: Chausse Calbet, Victor|||0000-0002-2644-6305, Schieber, Romain, Raymond Llorens, Santiago|||0000-0001-8302-3002, Ségry, Brian, Sabaté, Ramon, Kolandaivelu, Kumaran, Ginebra Molins, Maria Pau|||0000-0002-4700-5621, Pegueroles Neyra, Marta|||0000-0002-7895-8337
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/360840
Acceso en línea:https://hdl.handle.net/2117/360840
https://dx.doi.org/10.1016/j.addma.2021.102392
Access Level:acceso abierto
Palabra clave:Tissue engineering
Biomedical materials
Biomedical engineering
X-Rays
Solvent-cast direct-writing
Bioresorbable stents
Poly-l-lactic acid
Radiopacity
X-Ray imaging
Enginyeria de teixits
Materials biomèdics
Enginyeria biomèdica
Raigs X
Àrees temàtiques de la UPC::Enginyeria dels materials
id ES_7da71d0d4e8a48770038c934bf1b3546
oai_identifier_str oai:upcommons.upc.edu:2117/360840
network_acronym_str ES
network_name_str España
repository_id_str
spelling Solvent-cast direct-writing as a fabrication strategy for radiopaque stentsChausse Calbet, Victor|||0000-0002-2644-6305Schieber, RomainRaymond Llorens, Santiago|||0000-0001-8302-3002Ségry, BrianSabaté, RamonKolandaivelu, KumaranGinebra Molins, Maria Pau|||0000-0002-4700-5621Pegueroles Neyra, Marta|||0000-0002-7895-8337Tissue engineeringBiomedical materialsBiomedical engineeringX-RaysSolvent-cast direct-writingBioresorbable stentsPoly-l-lactic acidRadiopacityX-Ray imagingEnginyeria de teixitsMaterials biomèdicsEnginyeria biomèdicaRaigs XÀrees temàtiques de la UPC::Enginyeria dels materialsBioresorbable stents (BRS) potential in treating coronary heart disease is still to be further developed. Current trends include research with new polymeric materials, the need for thinner struts combined with appropriate mechanical properties, radiopacity and optimized local drug delivery. This work presents a novel solvent-cast direct-write (SC-DW) printing system to manufacture BRS onto a rotating cylinder with poly-l-lactic acid (PLLA) and poly(l-lactic-co- ¿ -caprolactone) (PLCL) inks. Printed stents were characterized in terms of mechanical, thermal and biological properties with human umbilical vein endothelial cells (HUVECs). Expansion assays showed that stents withstood pressures of at least 16 atm and the indirect cytotoxicity test indicated that stents were biocompatible. Polymeric inks were further modified with the addition of 3 radiopaque agents, namely iodine, triiodobenzoic acid (TIBA) and barium sulfate (BaSO) to render stents radiopaque. Subsequent characterization showed a general increase in strut thickness with respect to control PLLA or PLCL stents, which in turn resulted in higher resistance to compression. Microcomputed tomography was used to assess stents’ radiopacity, showing that TIBA and BaSO-containing stents presented high X-ray attenuation values and maintained their radiopacity after 3 months incubation time.Peer ReviewedElsevier20212021-12-0120222022-01-27journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/360840https://dx.doi.org/10.1016/j.addma.2021.102392reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/3608402026-05-27T15:37:01Z
dc.title.none.fl_str_mv Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
title Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
spellingShingle Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
Chausse Calbet, Victor|||0000-0002-2644-6305
Tissue engineering
Biomedical materials
Biomedical engineering
X-Rays
Solvent-cast direct-writing
Bioresorbable stents
Poly-l-lactic acid
Radiopacity
X-Ray imaging
Enginyeria de teixits
Materials biomèdics
Enginyeria biomèdica
Raigs X
Àrees temàtiques de la UPC::Enginyeria dels materials
title_short Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
title_full Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
title_fullStr Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
title_full_unstemmed Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
title_sort Solvent-cast direct-writing as a fabrication strategy for radiopaque stents
dc.creator.none.fl_str_mv Chausse Calbet, Victor|||0000-0002-2644-6305
Schieber, Romain
Raymond Llorens, Santiago|||0000-0001-8302-3002
Ségry, Brian
Sabaté, Ramon
Kolandaivelu, Kumaran
Ginebra Molins, Maria Pau|||0000-0002-4700-5621
Pegueroles Neyra, Marta|||0000-0002-7895-8337
author Chausse Calbet, Victor|||0000-0002-2644-6305
author_facet Chausse Calbet, Victor|||0000-0002-2644-6305
Schieber, Romain
Raymond Llorens, Santiago|||0000-0001-8302-3002
Ségry, Brian
Sabaté, Ramon
Kolandaivelu, Kumaran
Ginebra Molins, Maria Pau|||0000-0002-4700-5621
Pegueroles Neyra, Marta|||0000-0002-7895-8337
author_role author
author2 Schieber, Romain
Raymond Llorens, Santiago|||0000-0001-8302-3002
Ségry, Brian
Sabaté, Ramon
Kolandaivelu, Kumaran
Ginebra Molins, Maria Pau|||0000-0002-4700-5621
Pegueroles Neyra, Marta|||0000-0002-7895-8337
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Tissue engineering
Biomedical materials
Biomedical engineering
X-Rays
Solvent-cast direct-writing
Bioresorbable stents
Poly-l-lactic acid
Radiopacity
X-Ray imaging
Enginyeria de teixits
Materials biomèdics
Enginyeria biomèdica
Raigs X
Àrees temàtiques de la UPC::Enginyeria dels materials
topic Tissue engineering
Biomedical materials
Biomedical engineering
X-Rays
Solvent-cast direct-writing
Bioresorbable stents
Poly-l-lactic acid
Radiopacity
X-Ray imaging
Enginyeria de teixits
Materials biomèdics
Enginyeria biomèdica
Raigs X
Àrees temàtiques de la UPC::Enginyeria dels materials
description Bioresorbable stents (BRS) potential in treating coronary heart disease is still to be further developed. Current trends include research with new polymeric materials, the need for thinner struts combined with appropriate mechanical properties, radiopacity and optimized local drug delivery. This work presents a novel solvent-cast direct-write (SC-DW) printing system to manufacture BRS onto a rotating cylinder with poly-l-lactic acid (PLLA) and poly(l-lactic-co- ¿ -caprolactone) (PLCL) inks. Printed stents were characterized in terms of mechanical, thermal and biological properties with human umbilical vein endothelial cells (HUVECs). Expansion assays showed that stents withstood pressures of at least 16 atm and the indirect cytotoxicity test indicated that stents were biocompatible. Polymeric inks were further modified with the addition of 3 radiopaque agents, namely iodine, triiodobenzoic acid (TIBA) and barium sulfate (BaSO) to render stents radiopaque. Subsequent characterization showed a general increase in strut thickness with respect to control PLLA or PLCL stents, which in turn resulted in higher resistance to compression. Microcomputed tomography was used to assess stents’ radiopacity, showing that TIBA and BaSO-containing stents presented high X-ray attenuation values and maintained their radiopacity after 3 months incubation time.
publishDate 2021
dc.date.none.fl_str_mv 2021
2021-12-01
2022
2022-01-27
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/360840
https://dx.doi.org/10.1016/j.addma.2021.102392
url https://hdl.handle.net/2117/360840
https://dx.doi.org/10.1016/j.addma.2021.102392
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869411679551356928
score 15,300719