Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-CRP) techniques has become a powerful approach to tailor the chemical and physical properties of interfaces and has given rise to great advances in surface and interface engineering. Polymer brushes are defi...

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Detalles Bibliográficos
Autores: Zoppe, Justin Orazio|||0000-0002-3599-9227, Cavusoglu, Nariye, Mocny, Piotr, Wang, Jian, Moraes, John, Klok, Harm-Anton
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/336251
Acceso en línea:https://hdl.handle.net/2117/336251
https://dx.doi.org/10.1021/ACS.CHEMREV.6B00314
Access Level:acceso abierto
Palabra clave:Polymerization
Polimerització
Radicals (Química)
Àrees temàtiques de la UPC::Enginyeria química
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spelling Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushesZoppe, Justin Orazio|||0000-0002-3599-9227Cavusoglu, NariyeMocny, PiotrWang, JianMoraes, JohnKlok, Harm-AntonPolymerizationPolimeritzacióRadicals (Química)Àrees temàtiques de la UPC::Enginyeria químicaThe generation of polymer brushes by surface-initiated controlled radical polymerization (SI-CRP) techniques has become a powerful approach to tailor the chemical and physical properties of interfaces and has given rise to great advances in surface and interface engineering. Polymer brushes are defined as thin polymer films in which the individual polymer chains are tethered by one chain end to a solid interface. Significant advances have been made over the past years in the field of polymer brushes. This includes novel developments in SI-CRP, as well as the emergence of novel applications such as catalysis, electronics, nanomaterial synthesis and biosensing. Additionally, polymer brushes prepared via SI-CRP have been utilized to modify the surface of novel substrates such as natural fibers, polymer nanofibers, mesoporous materials, graphene, viruses and protein nanoparticles. The last years have also seen exciting advances in the chemical and physical characterization of polymer brushes, as well as an ever increasing set of computational and simulation tools that allow understanding and predictions of these surfacegrafted polymer architectures. The aim of this contribution is to provide a comprehensive review that critically assesses recent advances in the field and highlights the opportunities and challenges for future work.Peer Reviewed20172017-02-0820212021-02-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/336251https://dx.doi.org/10.1021/ACS.CHEMREV.6B00314reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivs 3.0 Spainhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/3362512026-05-27T15:37:01Z
dc.title.none.fl_str_mv Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
title Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
spellingShingle Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
Zoppe, Justin Orazio|||0000-0002-3599-9227
Polymerization
Polimerització
Radicals (Química)
Àrees temàtiques de la UPC::Enginyeria química
title_short Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
title_full Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
title_fullStr Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
title_full_unstemmed Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
title_sort Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
dc.creator.none.fl_str_mv Zoppe, Justin Orazio|||0000-0002-3599-9227
Cavusoglu, Nariye
Mocny, Piotr
Wang, Jian
Moraes, John
Klok, Harm-Anton
author Zoppe, Justin Orazio|||0000-0002-3599-9227
author_facet Zoppe, Justin Orazio|||0000-0002-3599-9227
Cavusoglu, Nariye
Mocny, Piotr
Wang, Jian
Moraes, John
Klok, Harm-Anton
author_role author
author2 Cavusoglu, Nariye
Mocny, Piotr
Wang, Jian
Moraes, John
Klok, Harm-Anton
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Polymerization
Polimerització
Radicals (Química)
Àrees temàtiques de la UPC::Enginyeria química
topic Polymerization
Polimerització
Radicals (Química)
Àrees temàtiques de la UPC::Enginyeria química
description The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-CRP) techniques has become a powerful approach to tailor the chemical and physical properties of interfaces and has given rise to great advances in surface and interface engineering. Polymer brushes are defined as thin polymer films in which the individual polymer chains are tethered by one chain end to a solid interface. Significant advances have been made over the past years in the field of polymer brushes. This includes novel developments in SI-CRP, as well as the emergence of novel applications such as catalysis, electronics, nanomaterial synthesis and biosensing. Additionally, polymer brushes prepared via SI-CRP have been utilized to modify the surface of novel substrates such as natural fibers, polymer nanofibers, mesoporous materials, graphene, viruses and protein nanoparticles. The last years have also seen exciting advances in the chemical and physical characterization of polymer brushes, as well as an ever increasing set of computational and simulation tools that allow understanding and predictions of these surfacegrafted polymer architectures. The aim of this contribution is to provide a comprehensive review that critically assesses recent advances in the field and highlights the opportunities and challenges for future work.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-02-08
2021
2021-02-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/336251
https://dx.doi.org/10.1021/ACS.CHEMREV.6B00314
url https://hdl.handle.net/2117/336251
https://dx.doi.org/10.1021/ACS.CHEMREV.6B00314
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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