Uniform, luminescent Eu:LuF3 nanoparticles

A simple procedure for the synthesis of orthorhombic, uniform, LuF3 particles with two different morphologies (rhombus- and cocoon-like) and nanometer and sub-micrometer size, respectively, is reported. The method consists in the aging, at 120 °C for 2 h, a solution containing [BMIM]BF4 ionic liquid...

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Detalles Bibliográficos
Autores: Becerro Nieto, Ana Isabel, González Mancebo, Daniel, Ocaña Jurado, Manuel
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2015
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/73026
Acceso en línea:https://hdl.handle.net/11441/73026
https://doi.org/10.1007/s11051-015-2874-z
Access Level:acceso abierto
Palabra clave:LuF3
Nanoparticles
Ionic liquid
Luminescence
Concentration quenching
Descripción
Sumario:A simple procedure for the synthesis of orthorhombic, uniform, LuF3 particles with two different morphologies (rhombus- and cocoon-like) and nanometer and sub-micrometer size, respectively, is reported. The method consists in the aging, at 120 °C for 2 h, a solution containing [BMIM]BF4 ionic liquid (0.5 mL) and lutetium acetate (in the case of the rhombi) or lutetium nitrate (in the case of the cocoons) (0.02 M) in ethylene glycol (total volume 10 mL). This synthesis method was also adequate for the synthesis of Eu3+-doped LuF3 particles of both morphologies, whose luminescence properties were investigated in detail. The experimental observations reported herein suggest that these materials are suitable phosphors for optoelectronic as well as in vitro biotechnological applications.