Non-ionic deep eutectic solvents for membrane formation

Deep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-me...

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Autores: Ismail, Norafiqah, Pan, Jun, Rahmati, Mahmoud, Wang, Qian, Bouyer, Denis, Khayet Souhaimi, Mohamed, Cui, Zhaoliang, Tavajohi, Naser
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/71781
Acceso en línea:https://hdl.handle.net/20.500.14352/71781
Access Level:acceso abierto
Palabra clave:536
Induced phase-separation
Hollow-fiber membrane
Poly(vinylidene fluoride) membranes
Waste-water treatment
Ultrafiltration uf membrane
Microporous membrane
Pvdf membranes
Polyvinylidene fluoride
Tips method
Crystallization kinetics
Termodinámica
2213 Termodinámica
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oai_identifier_str oai:docta.ucm.es:20.500.14352/71781
network_acronym_str ES
network_name_str España
repository_id_str
spelling Non-ionic deep eutectic solvents for membrane formationIsmail, NorafiqahPan, JunRahmati, MahmoudWang, QianBouyer, DenisKhayet Souhaimi, MohamedCui, ZhaoliangTavajohi, Naser536Induced phase-separationHollow-fiber membranePoly(vinylidene fluoride) membranesWaste-water treatmentUltrafiltration uf membraneMicroporous membranePvdf membranesPolyvinylidene fluorideTips methodCrystallization kineticsTermodinámica2213 TermodinámicaDeep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-methylacetamide-acetamide (DES-1), N-methyl acetamide-N-methyl urea (DES-2), and N-methyl acetamide-N,N & PRIME;-dimethyl urea (DES-3) were synthesized and used to dissolve polyvinylidene fluoride (PVDF) polymer. The effects of the additive polyvinylpyrrolidone (PVP) and the type of NIDES on the PVDF membrane characteristics, water permeability and bovine serum albumin (BSA) separation were studied. The membranes prepared with DES-1 and 2 wt% PVP exhibited a good water permeate flux (96.82 L/m(2).h) and a high BSA separation factor (96.32%). High performance PVDF membranes can thus be efficiently prepared using biodegradable inexpensive NIDES.Elsevier B. V.Universidad Complutense de Madrid20222022-03-1520222022-03-15journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/71781reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttps://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/717812026-06-02T12:44:21Z
dc.title.none.fl_str_mv Non-ionic deep eutectic solvents for membrane formation
title Non-ionic deep eutectic solvents for membrane formation
spellingShingle Non-ionic deep eutectic solvents for membrane formation
Ismail, Norafiqah
536
Induced phase-separation
Hollow-fiber membrane
Poly(vinylidene fluoride) membranes
Waste-water treatment
Ultrafiltration uf membrane
Microporous membrane
Pvdf membranes
Polyvinylidene fluoride
Tips method
Crystallization kinetics
Termodinámica
2213 Termodinámica
title_short Non-ionic deep eutectic solvents for membrane formation
title_full Non-ionic deep eutectic solvents for membrane formation
title_fullStr Non-ionic deep eutectic solvents for membrane formation
title_full_unstemmed Non-ionic deep eutectic solvents for membrane formation
title_sort Non-ionic deep eutectic solvents for membrane formation
dc.creator.none.fl_str_mv Ismail, Norafiqah
Pan, Jun
Rahmati, Mahmoud
Wang, Qian
Bouyer, Denis
Khayet Souhaimi, Mohamed
Cui, Zhaoliang
Tavajohi, Naser
author Ismail, Norafiqah
author_facet Ismail, Norafiqah
Pan, Jun
Rahmati, Mahmoud
Wang, Qian
Bouyer, Denis
Khayet Souhaimi, Mohamed
Cui, Zhaoliang
Tavajohi, Naser
author_role author
author2 Pan, Jun
Rahmati, Mahmoud
Wang, Qian
Bouyer, Denis
Khayet Souhaimi, Mohamed
Cui, Zhaoliang
Tavajohi, Naser
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 536
Induced phase-separation
Hollow-fiber membrane
Poly(vinylidene fluoride) membranes
Waste-water treatment
Ultrafiltration uf membrane
Microporous membrane
Pvdf membranes
Polyvinylidene fluoride
Tips method
Crystallization kinetics
Termodinámica
2213 Termodinámica
topic 536
Induced phase-separation
Hollow-fiber membrane
Poly(vinylidene fluoride) membranes
Waste-water treatment
Ultrafiltration uf membrane
Microporous membrane
Pvdf membranes
Polyvinylidene fluoride
Tips method
Crystallization kinetics
Termodinámica
2213 Termodinámica
description Deep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-methylacetamide-acetamide (DES-1), N-methyl acetamide-N-methyl urea (DES-2), and N-methyl acetamide-N,N & PRIME;-dimethyl urea (DES-3) were synthesized and used to dissolve polyvinylidene fluoride (PVDF) polymer. The effects of the additive polyvinylpyrrolidone (PVP) and the type of NIDES on the PVDF membrane characteristics, water permeability and bovine serum albumin (BSA) separation were studied. The membranes prepared with DES-1 and 2 wt% PVP exhibited a good water permeate flux (96.82 L/m(2).h) and a high BSA separation factor (96.32%). High performance PVDF membranes can thus be efficiently prepared using biodegradable inexpensive NIDES.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-03-15
2022
2022-03-15
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/71781
url https://hdl.handle.net/20.500.14352/71781
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
https://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
https://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier B. V.
publisher.none.fl_str_mv Elsevier B. V.
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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