Non-ionic deep eutectic solvents for membrane formation
Deep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-me...
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/71781 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/71781 |
| Access Level: | acceso abierto |
| Palabra clave: | 536 Induced phase-separation Hollow-fiber membrane Poly(vinylidene fluoride) membranes Waste-water treatment Ultrafiltration uf membrane Microporous membrane Pvdf membranes Polyvinylidene fluoride Tips method Crystallization kinetics Termodinámica 2213 Termodinámica |
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Non-ionic deep eutectic solvents for membrane formationIsmail, NorafiqahPan, JunRahmati, MahmoudWang, QianBouyer, DenisKhayet Souhaimi, MohamedCui, ZhaoliangTavajohi, Naser536Induced phase-separationHollow-fiber membranePoly(vinylidene fluoride) membranesWaste-water treatmentUltrafiltration uf membraneMicroporous membranePvdf membranesPolyvinylidene fluorideTips methodCrystallization kineticsTermodinámica2213 TermodinámicaDeep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-methylacetamide-acetamide (DES-1), N-methyl acetamide-N-methyl urea (DES-2), and N-methyl acetamide-N,N & PRIME;-dimethyl urea (DES-3) were synthesized and used to dissolve polyvinylidene fluoride (PVDF) polymer. The effects of the additive polyvinylpyrrolidone (PVP) and the type of NIDES on the PVDF membrane characteristics, water permeability and bovine serum albumin (BSA) separation were studied. The membranes prepared with DES-1 and 2 wt% PVP exhibited a good water permeate flux (96.82 L/m(2).h) and a high BSA separation factor (96.32%). High performance PVDF membranes can thus be efficiently prepared using biodegradable inexpensive NIDES.Elsevier B. V.Universidad Complutense de Madrid20222022-03-1520222022-03-15journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/71781reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttps://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/717812026-06-02T12:44:21Z |
| dc.title.none.fl_str_mv |
Non-ionic deep eutectic solvents for membrane formation |
| title |
Non-ionic deep eutectic solvents for membrane formation |
| spellingShingle |
Non-ionic deep eutectic solvents for membrane formation Ismail, Norafiqah 536 Induced phase-separation Hollow-fiber membrane Poly(vinylidene fluoride) membranes Waste-water treatment Ultrafiltration uf membrane Microporous membrane Pvdf membranes Polyvinylidene fluoride Tips method Crystallization kinetics Termodinámica 2213 Termodinámica |
| title_short |
Non-ionic deep eutectic solvents for membrane formation |
| title_full |
Non-ionic deep eutectic solvents for membrane formation |
| title_fullStr |
Non-ionic deep eutectic solvents for membrane formation |
| title_full_unstemmed |
Non-ionic deep eutectic solvents for membrane formation |
| title_sort |
Non-ionic deep eutectic solvents for membrane formation |
| dc.creator.none.fl_str_mv |
Ismail, Norafiqah Pan, Jun Rahmati, Mahmoud Wang, Qian Bouyer, Denis Khayet Souhaimi, Mohamed Cui, Zhaoliang Tavajohi, Naser |
| author |
Ismail, Norafiqah |
| author_facet |
Ismail, Norafiqah Pan, Jun Rahmati, Mahmoud Wang, Qian Bouyer, Denis Khayet Souhaimi, Mohamed Cui, Zhaoliang Tavajohi, Naser |
| author_role |
author |
| author2 |
Pan, Jun Rahmati, Mahmoud Wang, Qian Bouyer, Denis Khayet Souhaimi, Mohamed Cui, Zhaoliang Tavajohi, Naser |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
Universidad Complutense de Madrid |
| dc.subject.none.fl_str_mv |
536 Induced phase-separation Hollow-fiber membrane Poly(vinylidene fluoride) membranes Waste-water treatment Ultrafiltration uf membrane Microporous membrane Pvdf membranes Polyvinylidene fluoride Tips method Crystallization kinetics Termodinámica 2213 Termodinámica |
| topic |
536 Induced phase-separation Hollow-fiber membrane Poly(vinylidene fluoride) membranes Waste-water treatment Ultrafiltration uf membrane Microporous membrane Pvdf membranes Polyvinylidene fluoride Tips method Crystallization kinetics Termodinámica 2213 Termodinámica |
| description |
Deep eutectic solvents (DES) have recently emerged as a new class of inexpensive biodegradable solvents and additives with diverse applications. In this study, a new family of non-ionic deep eutectic solvents (NIDES) is proposed for the first time for membrane preparation. Three types of NIDES, N-methylacetamide-acetamide (DES-1), N-methyl acetamide-N-methyl urea (DES-2), and N-methyl acetamide-N,N & PRIME;-dimethyl urea (DES-3) were synthesized and used to dissolve polyvinylidene fluoride (PVDF) polymer. The effects of the additive polyvinylpyrrolidone (PVP) and the type of NIDES on the PVDF membrane characteristics, water permeability and bovine serum albumin (BSA) separation were studied. The membranes prepared with DES-1 and 2 wt% PVP exhibited a good water permeate flux (96.82 L/m(2).h) and a high BSA separation factor (96.32%). High performance PVDF membranes can thus be efficiently prepared using biodegradable inexpensive NIDES. |
| publishDate |
2022 |
| dc.date.none.fl_str_mv |
2022 2022-03-15 2022 2022-03-15 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/20.500.14352/71781 |
| url |
https://hdl.handle.net/20.500.14352/71781 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Atribución-NoComercial-SinDerivadas 3.0 España https://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Atribución-NoComercial-SinDerivadas 3.0 España https://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier B. V. |
| publisher.none.fl_str_mv |
Elsevier B. V. |
| dc.source.none.fl_str_mv |
reponame:Docta Complutense instname:Universidad Complutense de Madrid (UCM) |
| instname_str |
Universidad Complutense de Madrid (UCM) |
| reponame_str |
Docta Complutense |
| collection |
Docta Complutense |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
|
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1869411641545719808 |
| score |
15,301603 |