Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase

El mateix article està publicat a l'edició alemanya de la revista 'Angewandte chemie' (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374

Detalles Bibliográficos
Autores: Andris, Erik, Jašík, Juraj, Gómez Martín, Laura, Costas Salgueiro, Miquel, Roithová, Jana
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/12248
Acceso en línea:http://hdl.handle.net/10256/12248
Access Level:acceso abierto
Palabra clave:Catalitzadors
Catalysts
Espectroscòpia infraroja
Infrared spectroscopy
Ferro -- Compostos -- Oxidació
Iron compounds -- Oxidation
Espectrometria de masses
Mass spectrometry
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spelling Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas PhaseAndris, ErikJašík, JurajGómez Martín, LauraCostas Salgueiro, MiquelRoithová, JanaCatalitzadorsCatalystsEspectroscòpia infrarojaInfrared spectroscopyFerro -- Compostos -- OxidacióIron compounds -- OxidationEspectrometria de massesMass spectrometryEl mateix article està publicat a l'edició alemanya de la revista 'Angewandte chemie' (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass-selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin stateThis research was supported by the European Research Council (StG ISORI and BIDECASEOX), the Grant agency of the Czech Republic (14-20077S), the Spanish MINECO (CTQ2012-37420-C02-01/BQU), and an ICREA Academia Award to M.C. Computational resources were provided by the MetaCentrum under the program LM2010005 and the CERIT-SC under the program Centre CERIT Scientific Cloud, part of the Operational Program Research and Development for Innovations, Reg. no. CZ.1.05/3.2.00/08.0144Wiley-VCH VerlagMinisterio de Economía y Competitividad (Espanya)2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10256/12248http://hdl.handle.net/10256/12248Angewandte Chemie International Edition, 2016, vol. 55, núm. 11, p. 3637-3641Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201511374info:eu-repo/semantics/altIdentifier/issn/1433-7851info:eu-repo/semantics/altIdentifier/eissn/1521-3773info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01Attribution-NonCommercial 3.0 Spainhttp://creativecommons.org/licenses/by-nc/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:10256/122482026-05-29T05:05:01Z
dc.title.none.fl_str_mv Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
title Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
spellingShingle Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
Andris, Erik
Catalitzadors
Catalysts
Espectroscòpia infraroja
Infrared spectroscopy
Ferro -- Compostos -- Oxidació
Iron compounds -- Oxidation
Espectrometria de masses
Mass spectrometry
title_short Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
title_full Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
title_fullStr Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
title_full_unstemmed Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
title_sort Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
dc.creator.none.fl_str_mv Andris, Erik
Jašík, Juraj
Gómez Martín, Laura
Costas Salgueiro, Miquel
Roithová, Jana
author Andris, Erik
author_facet Andris, Erik
Jašík, Juraj
Gómez Martín, Laura
Costas Salgueiro, Miquel
Roithová, Jana
author_role author
author2 Jašík, Juraj
Gómez Martín, Laura
Costas Salgueiro, Miquel
Roithová, Jana
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (Espanya)
dc.subject.none.fl_str_mv Catalitzadors
Catalysts
Espectroscòpia infraroja
Infrared spectroscopy
Ferro -- Compostos -- Oxidació
Iron compounds -- Oxidation
Espectrometria de masses
Mass spectrometry
topic Catalitzadors
Catalysts
Espectroscòpia infraroja
Infrared spectroscopy
Ferro -- Compostos -- Oxidació
Iron compounds -- Oxidation
Espectrometria de masses
Mass spectrometry
description El mateix article està publicat a l'edició alemanya de la revista 'Angewandte chemie' (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/12248
http://hdl.handle.net/10256/12248
url http://hdl.handle.net/10256/12248
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201511374
info:eu-repo/semantics/altIdentifier/issn/1433-7851
info:eu-repo/semantics/altIdentifier/eissn/1521-3773
info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01
dc.rights.none.fl_str_mv Attribution-NonCommercial 3.0 Spain
http://creativecommons.org/licenses/by-nc/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial 3.0 Spain
http://creativecommons.org/licenses/by-nc/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH Verlag
publisher.none.fl_str_mv Wiley-VCH Verlag
dc.source.none.fl_str_mv Angewandte Chemie International Edition, 2016, vol. 55, núm. 11, p. 3637-3641
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812455

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