Thiol-based H2O2 signalling in microbial systems

Cysteine residues, and in particular their thiolate groups, react not only with reactive oxygen species but also with electrophiles and with reactive nitrogen species. Thus, cysteine oxidation has often been linked to the toxic effects of some of these reactive molecules. However, thiol-based switch...

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Detalles Bibliográficos
Autores: Boronat i Llop, Susanna, 1965-, Domènech, Alba, Paulo Mirasol, Esther, 1984-, Calvo, Isabel A., García Santamarina, Sarela, 1978-, García, Patrícia, Encinar del Dedo, Javier, Barcons-Simon, Anna, Serrano, Erica, Carmona, Mercè, Hidalgo Hernando, Elena
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Institución:Universitat Pompeu Fabra
Repositorio:Repositorio Digital de la UPF
OAI Identifier:oai:repositori.upf.edu:10230/23855
Acceso en línea:http://hdl.handle.net/10230/23855
http://dx.doi.org/10.1016/j.redox.2014.01.015
Access Level:acceso abierto
Palabra clave:Escheríchia coli
Saccharomyces cerevisiae -- Metabolisme
Schizosaccharomyces pombe -- Metabolisme
H2O2 sensor
Cys oxidation
OxyR
Pap1
Yap1
S. pombe
Descripción
Sumario:Cysteine residues, and in particular their thiolate groups, react not only with reactive oxygen species but also with electrophiles and with reactive nitrogen species. Thus, cysteine oxidation has often been linked to the toxic effects of some of these reactive molecules. However, thiol-based switches are common in protein sensors of antioxidant cascades, in both prokaryotic and eukaryotic organisms. We will describe here three redox sensors, the transcription factors OxyR, Yap1 and Pap1, which respond by disulfide bond formation to hydrogen peroxide stress, focusing specially on the differences among the three peroxide-sensing mechanisms.