Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy

Background/Objectives : YAT2150 is a first-in-class antiplasmodial compound that has been recently proposed as a new interesting drug for malaria therapy. Methods/Results : The fluorescence of YAT2150 rapidly increases upon its entry into Plasmodium, a property that can be of use for the design of h...

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Authors: Camarero-Hoyos, Claudia, Bouzón-Arnáiz, Inés, Avalos-Padilla, Yunuen|||0000-0003-4074-5624, Fallica, Antonino Nicolò|||0000-0003-1899-8414, Román-Álamo, Lucía, Ramírez Moreno, Miriam|||0000-0002-9823-319X, Portabella, Emma, Cuspinera, Ona, Currea-Ayala, Daniela, Orozco-Quer, Marc, Ribera, Maria, Siden-Kiamos, Inga|||0000-0003-1572-5840, Spanos, Lefteris, Iglesias, Valentin|||0000-0002-6133-0869, Crespo, Benigno, Viera, Sara|||0000-0002-2025-4804, Andreu Martínez, David|||0000-0002-6317-6666, Sulleiro, Elena|||0000-0002-9783-6060, Zarzuela, Francesc, Urtasun, Nerea|||0000-0003-1093-2269, Pérez-Torras, Sandra|||0000-0002-2785-5602, Pastor-Anglada, Marçal|||0000-0003-3712-1773, Arce, Elsa M.|||0000-0003-3757-5468, Muñoz-Torrero López-Ibarra, Diego|||0000-0002-8140-8555, Fernández Busquets, Xavier|||0000-0002-4622-9631
Format: article
Publication Date:2024
Country:España
Institution:Universitat Autònoma de Barcelona
Repository:Dipòsit Digital de Documents de la UAB
Language:English
OAI Identifier:oai:ddd.uab.cat:307581
Online Access:https://ddd.uab.cat/record/307581
https://dx.doi.org/urn:doi:10.3390/pharmaceutics16101290
Access Level:Open access
Keyword:Plasmodium falciparum
Malaria
Protein aggregation
YAT2150
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oai_identifier_str oai:ddd.uab.cat:307581
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
title Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
spellingShingle Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
Camarero-Hoyos, Claudia
Plasmodium falciparum
Malaria
Protein aggregation
YAT2150
title_short Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
title_full Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
title_fullStr Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
title_full_unstemmed Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
title_sort Leveraging the Aggregated Protein Dye YAT2150 for Malaria Chemotherapy
dc.creator.none.fl_str_mv Camarero-Hoyos, Claudia
Bouzón-Arnáiz, Inés
Avalos-Padilla, Yunuen|||0000-0003-4074-5624
Fallica, Antonino Nicolò|||0000-0003-1899-8414
Román-Álamo, Lucía
Ramírez Moreno, Miriam|||0000-0002-9823-319X
Portabella, Emma
Cuspinera, Ona
Currea-Ayala, Daniela
Orozco-Quer, Marc
Ribera, Maria
Siden-Kiamos, Inga|||0000-0003-1572-5840
Spanos, Lefteris
Iglesias, Valentin|||0000-0002-6133-0869
Crespo, Benigno
Viera, Sara|||0000-0002-2025-4804
Andreu Martínez, David|||0000-0002-6317-6666
Sulleiro, Elena|||0000-0002-9783-6060
Zarzuela, Francesc
Urtasun, Nerea|||0000-0003-1093-2269
Pérez-Torras, Sandra|||0000-0002-2785-5602
Pastor-Anglada, Marçal|||0000-0003-3712-1773
Arce, Elsa M.|||0000-0003-3757-5468
Muñoz-Torrero López-Ibarra, Diego|||0000-0002-8140-8555
Fernández Busquets, Xavier|||0000-0002-4622-9631
author Camarero-Hoyos, Claudia
author_facet Camarero-Hoyos, Claudia
Bouzón-Arnáiz, Inés
Avalos-Padilla, Yunuen|||0000-0003-4074-5624
Fallica, Antonino Nicolò|||0000-0003-1899-8414
Román-Álamo, Lucía
Ramírez Moreno, Miriam|||0000-0002-9823-319X
Portabella, Emma
Cuspinera, Ona
Currea-Ayala, Daniela
Orozco-Quer, Marc
Ribera, Maria
Siden-Kiamos, Inga|||0000-0003-1572-5840
Spanos, Lefteris
Iglesias, Valentin|||0000-0002-6133-0869
Crespo, Benigno
Viera, Sara|||0000-0002-2025-4804
Andreu Martínez, David|||0000-0002-6317-6666
Sulleiro, Elena|||0000-0002-9783-6060
Zarzuela, Francesc
Urtasun, Nerea|||0000-0003-1093-2269
Pérez-Torras, Sandra|||0000-0002-2785-5602
Pastor-Anglada, Marçal|||0000-0003-3712-1773
Arce, Elsa M.|||0000-0003-3757-5468
Muñoz-Torrero López-Ibarra, Diego|||0000-0002-8140-8555
Fernández Busquets, Xavier|||0000-0002-4622-9631
author_role author
author2 Bouzón-Arnáiz, Inés
Avalos-Padilla, Yunuen|||0000-0003-4074-5624
Fallica, Antonino Nicolò|||0000-0003-1899-8414
Román-Álamo, Lucía
Ramírez Moreno, Miriam|||0000-0002-9823-319X
Portabella, Emma
Cuspinera, Ona
Currea-Ayala, Daniela
Orozco-Quer, Marc
Ribera, Maria
Siden-Kiamos, Inga|||0000-0003-1572-5840
Spanos, Lefteris
Iglesias, Valentin|||0000-0002-6133-0869
Crespo, Benigno
Viera, Sara|||0000-0002-2025-4804
Andreu Martínez, David|||0000-0002-6317-6666
Sulleiro, Elena|||0000-0002-9783-6060
Zarzuela, Francesc
Urtasun, Nerea|||0000-0003-1093-2269
Pérez-Torras, Sandra|||0000-0002-2785-5602
Pastor-Anglada, Marçal|||0000-0003-3712-1773
Arce, Elsa M.|||0000-0003-3757-5468
Muñoz-Torrero López-Ibarra, Diego|||0000-0002-8140-8555
Fernández Busquets, Xavier|||0000-0002-4622-9631
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Plasmodium falciparum
Malaria
Protein aggregation
YAT2150
topic Plasmodium falciparum
Malaria
Protein aggregation
YAT2150
description Background/Objectives : YAT2150 is a first-in-class antiplasmodial compound that has been recently proposed as a new interesting drug for malaria therapy. Methods/Results : The fluorescence of YAT2150 rapidly increases upon its entry into Plasmodium, a property that can be of use for the design of highly sensitive diagnostic approaches. YAT2150 blocks the in vitro development of the ookinete stage of Plasmodium and, when added to an infected blood meal, inhibits oocyst formation in the mosquito. Thus, the compound could possibly contribute to future transmission-blocking antimalarial strategies. Cell influx/efflux studies in Caco-2 cells suggest that YAT2150 is internalized by endocytosis and also through the OATP2B1 transporter, whereas its main export route would be via OSTα. YAT2150 has an overall favorable drug metabolism and pharmacokinetics profile, and its moderate cytotoxicity can be significantly reduced upon encapsulation in immunoliposomes, which leads to a dramatic increase in the drug selectivity index to values close to 1000. Although YAT2150 binds amyloid-forming peptides, its in vitro fluorescence emission is stronger upon association with peptides that form amorphous aggregates, suggesting that regions enriched in unstructured proteins are the preferential binding sites of the drug inside Plasmodium cells. The reduction of protein aggregation in the parasite after YAT2150 treatment, which has been suggested to be directly related to the drug's mode of action, is also observed following treatment with quinoline antimalarials like chloroquine and primaquine. Conclusions : Altogether, the data presented here indicate that YAT2150 can represent the spearhead of a new family of compounds for malaria diagnosis and therapy due to its presumed novel mode of action based on the interaction with functional protein aggregates in the pathogen.
publishDate 2024
dc.date.none.fl_str_mv 2
2024-01-01
2024
2024-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/307581
https://dx.doi.org/urn:doi:10.3390/pharmaceutics16101290
url https://ddd.uab.cat/record/307581
https://dx.doi.org/urn:doi:10.3390/pharmaceutics16101290
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-128325OB-I00
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PDC2022-133085-I00
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2020-118127RB-I00
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 AGL2017-84097-C2-2-R
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-124765OB-I00
Generalitat de Catalunya https://doi.org/10.13039/501100002809 2021SGR00635
Generalitat de Catalunya https://doi.org/10.13039/501100002809 2021SGR00357
"la Caixa" Foundation https://doi.org/10.13039/100010434 HR1700409
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
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rights_invalid_str_mv open access
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dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
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spelling Leveraging the Aggregated Protein Dye YAT2150 for Malaria ChemotherapyCamarero-Hoyos, ClaudiaBouzón-Arnáiz, InésAvalos-Padilla, Yunuen|||0000-0003-4074-5624Fallica, Antonino Nicolò|||0000-0003-1899-8414Román-Álamo, LucíaRamírez Moreno, Miriam|||0000-0002-9823-319XPortabella, EmmaCuspinera, OnaCurrea-Ayala, DanielaOrozco-Quer, MarcRibera, MariaSiden-Kiamos, Inga|||0000-0003-1572-5840Spanos, LefterisIglesias, Valentin|||0000-0002-6133-0869Crespo, BenignoViera, Sara|||0000-0002-2025-4804Andreu Martínez, David|||0000-0002-6317-6666Sulleiro, Elena|||0000-0002-9783-6060Zarzuela, FrancescUrtasun, Nerea|||0000-0003-1093-2269Pérez-Torras, Sandra|||0000-0002-2785-5602Pastor-Anglada, Marçal|||0000-0003-3712-1773Arce, Elsa M.|||0000-0003-3757-5468Muñoz-Torrero López-Ibarra, Diego|||0000-0002-8140-8555Fernández Busquets, Xavier|||0000-0002-4622-9631Plasmodium falciparumMalariaProtein aggregationYAT2150Background/Objectives : YAT2150 is a first-in-class antiplasmodial compound that has been recently proposed as a new interesting drug for malaria therapy. Methods/Results : The fluorescence of YAT2150 rapidly increases upon its entry into Plasmodium, a property that can be of use for the design of highly sensitive diagnostic approaches. YAT2150 blocks the in vitro development of the ookinete stage of Plasmodium and, when added to an infected blood meal, inhibits oocyst formation in the mosquito. Thus, the compound could possibly contribute to future transmission-blocking antimalarial strategies. Cell influx/efflux studies in Caco-2 cells suggest that YAT2150 is internalized by endocytosis and also through the OATP2B1 transporter, whereas its main export route would be via OSTα. YAT2150 has an overall favorable drug metabolism and pharmacokinetics profile, and its moderate cytotoxicity can be significantly reduced upon encapsulation in immunoliposomes, which leads to a dramatic increase in the drug selectivity index to values close to 1000. Although YAT2150 binds amyloid-forming peptides, its in vitro fluorescence emission is stronger upon association with peptides that form amorphous aggregates, suggesting that regions enriched in unstructured proteins are the preferential binding sites of the drug inside Plasmodium cells. The reduction of protein aggregation in the parasite after YAT2150 treatment, which has been suggested to be directly related to the drug's mode of action, is also observed following treatment with quinoline antimalarials like chloroquine and primaquine. Conclusions : Altogether, the data presented here indicate that YAT2150 can represent the spearhead of a new family of compounds for malaria diagnosis and therapy due to its presumed novel mode of action based on the interaction with functional protein aggregates in the pathogen. 22024-01-0120242024-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/307581https://dx.doi.org/urn:doi:10.3390/pharmaceutics16101290reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-128325OB-I00Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PDC2022-133085-I00Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2020-118127RB-I00Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 AGL2017-84097-C2-2-RAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-124765OB-I00Generalitat de Catalunya https://doi.org/10.13039/501100002809 2021SGR00635Generalitat de Catalunya https://doi.org/10.13039/501100002809 2021SGR00357"la Caixa" Foundation https://doi.org/10.13039/100010434 HR1700409open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:3075812026-06-06T12:50:31Z
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