Controlled dopamine release from cellulose-based conducting hydrogel

Very recently, the controlled release of dopamine (DA), a neurotransmitter whose deficiency is associated with Parkinson's disease, has been postulated as a good alternative to the oral administration of levodopa (L-Dopa), a dopamine precursor, to combat the effects of said disease. However, th...

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Detalles Bibliográficos
Autores: Molina García, Brenda Guadalupe|||0000-0002-7723-5313, Arnau Roca, Marc|||0000-0001-6038-3902, Sánchez Jiménez, Margarita|||0000-0003-4375-6230, Alemán Llansó, Carlos|||0000-0003-4462-6075
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/401534
Acceso en línea:https://hdl.handle.net/2117/401534
https://dx.doi.org/10.1016/j.eurpolymj.2023.112635
Access Level:acceso abierto
Palabra clave:Conducting polymers
Neurotransmitters
Conducting hydrogels
Carboxymethylcellulose
Neurotransmitters release
Electrostimulation
Polímers conductors
Neurotransmissors
Àrees temàtiques de la UPC::Enginyeria química
Descripción
Sumario:Very recently, the controlled release of dopamine (DA), a neurotransmitter whose deficiency is associated with Parkinson's disease, has been postulated as a good alternative to the oral administration of levodopa (L-Dopa), a dopamine precursor, to combat the effects of said disease. However, this is still a very little explored field and there are very few carriers that are capable of releasing DA, a small and water-soluble molecule, in an efficient and controlled manner. In this work, we report a carrier based on a conductive hydrogel capable of loading DA and releasing it progressively and efficiently (100 % release) in a period of five days by applying small electrical stimuli (–0.4 V) daily for a short time (1 min). The hydrogel (CMC/PEDOT), which is electrically active, has been prepared from sodium carboxymethylcellulose and poly(3,4-ethylenedioxythiophene) microparticles, using citric acid as a cross-linking agent. Furthermore, the results have shown that when relatively hydrophobic small molecules, such as chloramphenicol, are loaded, the electrostimulated release is significantly less efficient, demonstrating the usefulness of CMC/PEDOT as a carrier for neurotransmitters.