Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands

Multifunctional molecules that respond both to magnetic fields and light are subject of study due to possible applications in fields as diverse as imaging or information processing and storage. In this paper we report visible and NIR emitting single-molecule magnets (SMMs) of Yb(III) and Er(III) wit...

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Autores: Gholizadeh Dogaheh, Samira, Khanmohammadi, Hamid, Sañudo Zotes, Eva Carolina
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/125847
Acceso en línea:https://hdl.handle.net/2445/125847
Access Level:acceso abierto
Palabra clave:Lligands (Bioquímica)
Camps magnètics
Propietats magnètiques
Ligands (Biochemistry)
Magnetic fields
Magnetic properties
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spelling Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligandsGholizadeh Dogaheh, SamiraKhanmohammadi, HamidSañudo Zotes, Eva CarolinaLligands (Bioquímica)Camps magnèticsPropietats magnètiquesLigands (Biochemistry)Magnetic fieldsMagnetic propertiesMultifunctional molecules that respond both to magnetic fields and light are subject of study due to possible applications in fields as diverse as imaging or information processing and storage. In this paper we report visible and NIR emitting single-molecule magnets (SMMs) of Yb(III) and Er(III) with symmetric (SYML) and asymmetric (AZOL) Schiff base ligands. The prepared complexes SYML-Ln2 and AZOL-Ln3 (Ln = Er, Yb) are SMMs, with the exception of AZOL-Yb3, with a relaxation behavior dominated by quantum tunneling of magnetization. The multi-level double-decker structure of the complexes is ideal for surface deposition in carbon-based materials.Royal Society of Chemistry2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/125847Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: https://doi.org/10.1039/c7nj01842hNew Journal of Chemistry, 2017, vol. 41, p. 10101-10111https://doi.org/10.1039/c7nj01842h(c) Gholizadeh Dogaheh, Samira et al., 2017info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1258472026-05-27T06:46:51Z
dc.title.none.fl_str_mv Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
title Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
spellingShingle Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
Gholizadeh Dogaheh, Samira
Lligands (Bioquímica)
Camps magnètics
Propietats magnètiques
Ligands (Biochemistry)
Magnetic fields
Magnetic properties
title_short Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
title_full Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
title_fullStr Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
title_full_unstemmed Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
title_sort Double decker luminescent Ytterbium and Erbium SMMs with symmetric and asymmetric Schiff base ligands
dc.creator.none.fl_str_mv Gholizadeh Dogaheh, Samira
Khanmohammadi, Hamid
Sañudo Zotes, Eva Carolina
author Gholizadeh Dogaheh, Samira
author_facet Gholizadeh Dogaheh, Samira
Khanmohammadi, Hamid
Sañudo Zotes, Eva Carolina
author_role author
author2 Khanmohammadi, Hamid
Sañudo Zotes, Eva Carolina
author2_role author
author
dc.subject.none.fl_str_mv Lligands (Bioquímica)
Camps magnètics
Propietats magnètiques
Ligands (Biochemistry)
Magnetic fields
Magnetic properties
topic Lligands (Bioquímica)
Camps magnètics
Propietats magnètiques
Ligands (Biochemistry)
Magnetic fields
Magnetic properties
description Multifunctional molecules that respond both to magnetic fields and light are subject of study due to possible applications in fields as diverse as imaging or information processing and storage. In this paper we report visible and NIR emitting single-molecule magnets (SMMs) of Yb(III) and Er(III) with symmetric (SYML) and asymmetric (AZOL) Schiff base ligands. The prepared complexes SYML-Ln2 and AZOL-Ln3 (Ln = Er, Yb) are SMMs, with the exception of AZOL-Yb3, with a relaxation behavior dominated by quantum tunneling of magnetization. The multi-level double-decker structure of the complexes is ideal for surface deposition in carbon-based materials.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/125847
url https://hdl.handle.net/2445/125847
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1039/c7nj01842h
New Journal of Chemistry, 2017, vol. 41, p. 10101-10111
https://doi.org/10.1039/c7nj01842h
dc.rights.none.fl_str_mv (c) Gholizadeh Dogaheh, Samira et al., 2017
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Gholizadeh Dogaheh, Samira et al., 2017
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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