Porosity and hydric behavior of typical calcite microfabrics in stalagmites

Petrophysical techniques commonly used for material characterization are applied for the first time to speleothem samples to investigate the porosity and hydric behavior of calcite stalagmites used in paleoclimatology. These techniques allow the determination of the stalagmites' potential to un...

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Detalles Bibliográficos
Autores: Muñoz García, Mercedes, López Arce, Paula, Fernández Valle, Mª Encarnación, Martín Chivelet, Javier, Fort González, Rafael
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/43667
Acceso en línea:https://hdl.handle.net/20.500.14352/43667
Access Level:acceso abierto
Palabra clave:549.74:552.14
Speleothems
Diagenesis
Porosity
Hydric properties
Paleoclimate
Petrología
Descripción
Sumario:Petrophysical techniques commonly used for material characterization are applied for the first time to speleothem samples to investigate the porosity and hydric behavior of calcite stalagmites used in paleoclimatology. These techniques allow the determination of the stalagmites' potential to undergo diagenetic transformations when substantial changes in drip waters occur in the cave environment. The petrophysical techniques include water absorption under vacuum and by capillarity, nuclear magnetic resonance, environmental scanning electron microscopy, and mercury intrusion porosimetry. The studied samples comprise five common calcite microfabrics, which have markedly different porosities and hydric behaviors and, as a consequence, different sensibilities to diagenetic processes related to the influx of water. The experiments show that stalagmites can behave as complex, small-scale hydrological systems and that the circulation of water through them by complex nets of interconnected pores might be common. As the circulation of water favors diagenetic transformations that involve geochemical and isotopic changes, the characterization of flow patterns is key for outlining areas that are susceptible to such modifications, which is critical to paleoclimatic studies that are based on speleothems because geochemical and stable isotopic data are used as paleoenvironmental proxies and absolute ages are obtained by using radioactive isotope ratios. These potential modifications also have obvious implications for studies based on fluid inclusions in speleothems. The integrated methodology, which uses primarily non-destructive techniques, shows a high potential for characterization of any type of speleothem and other continental carbonates such as tufas or sinters.