The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide

Environmental mineralogy is rapidly expanding in technological directions that allow for the detection, characterization, and understanding of non-crystalline and poorly crystalline phases, crystalline-amorphous mixed phases, and nanosized naturally occurring materials. Specifically, this article pr...

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Detalles Bibliográficos
Autores: Caraballo Monge, Manuel Antonio, Michel, F. Marc, Hochella Jr., Michel F.
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/23137
Acceso en línea:https://hdl.handle.net/10272/23137
Access Level:acceso abierto
Palabra clave:Environmental mineralogy
Synchrotron radiation
Free electron laser
Transmission electron microscopy
Nanomineral
Mineral nanoparticle
Polyphasic nanomineral
Prenucleation cluster
Non-classical crystallization
Mesocrystal
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spelling The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guideCaraballo Monge, Manuel AntonioMichel, F. MarcHochella Jr., Michel F.Environmental mineralogySynchrotron radiationFree electron laserTransmission electron microscopyNanomineralMineral nanoparticlePolyphasic nanomineralPrenucleation clusterNon-classical crystallizationMesocrystalEnvironmental mineralogy is rapidly expanding in technological directions that allow for the detection, characterization, and understanding of non-crystalline and poorly crystalline phases, crystalline-amorphous mixed phases, and nanosized naturally occurring materials. Specifically, this article provides a perspective view of the broad range of structural complexity/heterogeneity observed in environmental minerals and amorphous materials, as well as our current understanding of how these materials can be best observed, evaluated, and described, and why this is important in the mineralogical sciences. The discussion is broken down into the assessment of short- and medium-range order in amorphous materials, and the nature of nanominerals and mineral nanoparticles, amorphous-nanocrystalline transitional phases, and mesocrystals. These materials do not fit one or more aspects of the most commonly used definitions of a mineral (although some of them are formally recognized as minerals, such as ferrihydrite and schwertmannite), yet they do fit other portions of these current definitions. Nevertheless, because these phases can be exceptionally minute in size, and/or not highly crystalline, and/or generally much less abundant than other mineral components in the system, they may be underappreciated and/or understudied, or, apparently as is often the case, completely missed. Yet they are often highly relevant to, and in many cases dominant in, important aspects of how the (bio)geochemistry of an environmental system operates. Furthermore, although it is important to analytically and experimentally characterize synthetic equivalent phases in the laboratory, often under conditions intended to mimic one or a few aspects of the real environment, we argue that it is imperative to study natural, intact (as much as possible) samples and make field measurements with much greater frequency than is currently practiced.Mineralogical Society of America20152015-01-0120152015-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10272/23137reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelvainstname:Universidad de Huelva (UHU)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:ariasmontano.uhu.es:10272/231372026-06-02T14:58:11Z
dc.title.none.fl_str_mv The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
title The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
spellingShingle The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
Caraballo Monge, Manuel Antonio
Environmental mineralogy
Synchrotron radiation
Free electron laser
Transmission electron microscopy
Nanomineral
Mineral nanoparticle
Polyphasic nanomineral
Prenucleation cluster
Non-classical crystallization
Mesocrystal
title_short The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
title_full The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
title_fullStr The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
title_full_unstemmed The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
title_sort The rapid expansion of environmental mineralogy in unconventional ways: Beyond the accepted definition of a mineral, the latest technology, and using nature as our guide
dc.creator.none.fl_str_mv Caraballo Monge, Manuel Antonio
Michel, F. Marc
Hochella Jr., Michel F.
author Caraballo Monge, Manuel Antonio
author_facet Caraballo Monge, Manuel Antonio
Michel, F. Marc
Hochella Jr., Michel F.
author_role author
author2 Michel, F. Marc
Hochella Jr., Michel F.
author2_role author
author
dc.contributor.none.fl_str_mv
dc.subject.none.fl_str_mv Environmental mineralogy
Synchrotron radiation
Free electron laser
Transmission electron microscopy
Nanomineral
Mineral nanoparticle
Polyphasic nanomineral
Prenucleation cluster
Non-classical crystallization
Mesocrystal
topic Environmental mineralogy
Synchrotron radiation
Free electron laser
Transmission electron microscopy
Nanomineral
Mineral nanoparticle
Polyphasic nanomineral
Prenucleation cluster
Non-classical crystallization
Mesocrystal
description Environmental mineralogy is rapidly expanding in technological directions that allow for the detection, characterization, and understanding of non-crystalline and poorly crystalline phases, crystalline-amorphous mixed phases, and nanosized naturally occurring materials. Specifically, this article provides a perspective view of the broad range of structural complexity/heterogeneity observed in environmental minerals and amorphous materials, as well as our current understanding of how these materials can be best observed, evaluated, and described, and why this is important in the mineralogical sciences. The discussion is broken down into the assessment of short- and medium-range order in amorphous materials, and the nature of nanominerals and mineral nanoparticles, amorphous-nanocrystalline transitional phases, and mesocrystals. These materials do not fit one or more aspects of the most commonly used definitions of a mineral (although some of them are formally recognized as minerals, such as ferrihydrite and schwertmannite), yet they do fit other portions of these current definitions. Nevertheless, because these phases can be exceptionally minute in size, and/or not highly crystalline, and/or generally much less abundant than other mineral components in the system, they may be underappreciated and/or understudied, or, apparently as is often the case, completely missed. Yet they are often highly relevant to, and in many cases dominant in, important aspects of how the (bio)geochemistry of an environmental system operates. Furthermore, although it is important to analytically and experimentally characterize synthetic equivalent phases in the laboratory, often under conditions intended to mimic one or a few aspects of the real environment, we argue that it is imperative to study natural, intact (as much as possible) samples and make field measurements with much greater frequency than is currently practiced.
publishDate 2015
dc.date.none.fl_str_mv 2015
2015-01-01
2015
2015-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10272/23137
url https://hdl.handle.net/10272/23137
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Mineralogical Society of America
publisher.none.fl_str_mv Mineralogical Society of America
dc.source.none.fl_str_mv reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelva
instname:Universidad de Huelva (UHU)
instname_str Universidad de Huelva (UHU)
reponame_str Arias Montano. Repositorio Institucional de la Universidad de Huelva
collection Arias Montano. Repositorio Institucional de la Universidad de Huelva
repository.name.fl_str_mv
repository.mail.fl_str_mv
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