Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles

[EN] Mesoporous silica nanoparticles (MSN) have been growing in recent years in a broad range of applications, such as nanomedicine, catalysis, and gas storage. For the preparation of MSN, especially in nanomedicine applications, the extraction of the surfactant template, generally 1-hexadecyltrimet...

Descripción completa

Detalles Bibliográficos
Autores: Candela-Noguera, Vicente, Aznar, Elena|||0000-0003-0361-3876, Marcos Martínez, María Dolores|||0000-0001-7079-8589, Martínez-Máñez, Ramón|||0000-0001-5873-9674, Amorós, Pedro
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/207624
Acceso en línea:https://riunet.upv.es/handle/10251/207624
Access Level:acceso abierto
Palabra clave:Mesoporous silica nanoparticles
Surfactant removal
Efficiency
Condensation degree
Porosity
Biocompatibility
Biodegradability
QUIMICA INORGANICA
id ES_79d05cf13f2c8479af3f2f70152f3bf9
oai_identifier_str oai:riunet.upv.es:10251/207624
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
title Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
spellingShingle Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
Candela-Noguera, Vicente
Mesoporous silica nanoparticles
Surfactant removal
Efficiency
Condensation degree
Porosity
Biocompatibility
Biodegradability
QUIMICA INORGANICA
title_short Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
title_full Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
title_fullStr Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
title_full_unstemmed Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
title_sort Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticles
dc.creator.none.fl_str_mv Candela-Noguera, Vicente
Aznar, Elena|||0000-0003-0361-3876
Marcos Martínez, María Dolores|||0000-0001-7079-8589
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Amorós, Pedro
author Candela-Noguera, Vicente
author_facet Candela-Noguera, Vicente
Aznar, Elena|||0000-0003-0361-3876
Marcos Martínez, María Dolores|||0000-0001-7079-8589
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Amorós, Pedro
author_role author
author2 Aznar, Elena|||0000-0003-0361-3876
Marcos Martínez, María Dolores|||0000-0001-7079-8589
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Amorós, Pedro
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial
Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico
Generalitat Valenciana
Agencia Estatal de Investigación
European Regional Development Fund
Ministerio de Ciencia e Innovación
Ministerio de Educación, Cultura y Deporte
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Mesoporous silica nanoparticles
Surfactant removal
Efficiency
Condensation degree
Porosity
Biocompatibility
Biodegradability
QUIMICA INORGANICA
topic Mesoporous silica nanoparticles
Surfactant removal
Efficiency
Condensation degree
Porosity
Biocompatibility
Biodegradability
QUIMICA INORGANICA
description [EN] Mesoporous silica nanoparticles (MSN) have been growing in recent years in a broad range of applications, such as nanomedicine, catalysis, and gas storage. For the preparation of MSN, especially in nanomedicine applications, the extraction of the surfactant template, generally 1-hexadecyltrimethylammonium bromide (CTAB), is required. Several methods to remove the surfactant from MNS have been reported in the literature, such as calcination, solvent extraction, and dialysis. Depending on the method employed, the materials obtained have different properties; however, a systematic study that compares the use of different surfactant extraction methods and their implications in the final characteristics of the MSN has not been reported. Hence, the aim of this work is to study the effect of surfactant removal on MSN by calcination at different temperatures (400 degrees C, 450 degrees C, 500 degrees C and 550 degrees C) or by extraction with HCl/ethanol or NH 4 NO 3 /ethanol. The final materials are fully characterised by different techniques. The study performed shows the removal efficiency when the different methods are used, and their effect on silica condensation degree, mesoporosity, cytotoxicity, and degradation rate. The results allow for obtaining a deeper knowledge of the surfactant removal processes.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-06-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/207624
url https://riunet.upv.es/handle/10251/207624
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126304OB-C41 NUEVOS MATERIALES Y SONDAS PARA EL RECONOCIMIENTO, LIBERACION DE FARMACOS, NANOMOTORES Y COMUNICACION
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126304OB-C43 SINTESIS Y APLICACIONES SELECCIONADAS DE NUEVOS NANOMATERIALES Y NANOCOMPUESTOS POROSOS MULTIFUNCIONALES
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-128141OB-C22 DESARROLLO DE NUEVOS MATERIALES INTELIGENTES Y SU APLICACION COMO SISTEMAS ANTIVIRALES, ANTIBIOFILM, ANTIENZIMATICOS Y ANTIMICROBIANOS PARA LA INDUSTRIA ALIMENTARIA.
Ministerio de Educación y Cultura http://dx.doi.org/10.13039/501100003176 FPU15%2F02753 FPU15%2F02753
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CB07%2F01%2F2012 Bioingeniería, biomateriales y nanomedicina
Generalitat Valenciana https://doi.org/10.13039/501100003359 CIPROM%2F2021%2F007
Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F049
Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F053
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 PRTR-C17.I1
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869411390614142976
spelling Systematic study of the implications of calcination and solvent extraction of the surfactant in MCM-41-type mesoporous silica nanoparticlesCandela-Noguera, VicenteAznar, Elena|||0000-0003-0361-3876Marcos Martínez, María Dolores|||0000-0001-7079-8589Martínez-Máñez, Ramón|||0000-0001-5873-9674Amorós, PedroMesoporous silica nanoparticlesSurfactant removalEfficiencyCondensation degreePorosityBiocompatibilityBiodegradabilityQUIMICA INORGANICA[EN] Mesoporous silica nanoparticles (MSN) have been growing in recent years in a broad range of applications, such as nanomedicine, catalysis, and gas storage. For the preparation of MSN, especially in nanomedicine applications, the extraction of the surfactant template, generally 1-hexadecyltrimethylammonium bromide (CTAB), is required. Several methods to remove the surfactant from MNS have been reported in the literature, such as calcination, solvent extraction, and dialysis. Depending on the method employed, the materials obtained have different properties; however, a systematic study that compares the use of different surfactant extraction methods and their implications in the final characteristics of the MSN has not been reported. Hence, the aim of this work is to study the effect of surfactant removal on MSN by calcination at different temperatures (400 degrees C, 450 degrees C, 500 degrees C and 550 degrees C) or by extraction with HCl/ethanol or NH 4 NO 3 /ethanol. The final materials are fully characterised by different techniques. The study performed shows the removal efficiency when the different methods are used, and their effect on silica condensation degree, mesoporosity, cytotoxicity, and degradation rate. The results allow for obtaining a deeper knowledge of the surfactant removal processes.V.C.-N. thanks the Spanish Government for his fellowship (FPU15/02753) . This research was supported by projects PID2021-126304OB-C41, PID2021-126304OB-C43 and PID2021-128141OB-C22 funded by MCIN/AEI/10.13039/501100011033/and by European Regional Development Fund-Away of doing Europe. This study also forms part of the Advanced Materials programme (MFA/2022/049 and MFA/2022/053) and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat Valenciana. This study was also supported by Generalitat Valenciana (CIPROM/2021/007) . This research was also supported by CIBER-Consorcio Centro de Investigacion Biomedica en Red- (CB07/01/2012) , Instituto de Salud Carlos III, Ministerio de Ciencia e Innovacion. The authors also thank the Electron Microscopy Service at UPV and SCSIE at UV for support. NMR was registered at the U26 facility of ICTS "NANBIOSIS" at the Universitat of Valencia.ElsevierEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialInstituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo TecnológicoGeneralitat ValencianaAgencia Estatal de InvestigaciónEuropean Regional Development FundMinisterio de Ciencia e InnovaciónMinisterio de Educación, Cultura y DeporteUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-06-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/207624reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126304OB-C41 NUEVOS MATERIALES Y SONDAS PARA EL RECONOCIMIENTO, LIBERACION DE FARMACOS, NANOMOTORES Y COMUNICACIONAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-126304OB-C43 SINTESIS Y APLICACIONES SELECCIONADAS DE NUEVOS NANOMATERIALES Y NANOCOMPUESTOS POROSOS MULTIFUNCIONALESAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-128141OB-C22 DESARROLLO DE NUEVOS MATERIALES INTELIGENTES Y SU APLICACION COMO SISTEMAS ANTIVIRALES, ANTIBIOFILM, ANTIENZIMATICOS Y ANTIMICROBIANOS PARA LA INDUSTRIA ALIMENTARIA.Ministerio de Educación y Cultura http://dx.doi.org/10.13039/501100003176 FPU15%2F02753 FPU15%2F02753Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CB07%2F01%2F2012 Bioingeniería, biomateriales y nanomedicinaGeneralitat Valenciana https://doi.org/10.13039/501100003359 CIPROM%2F2021%2F007Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F049Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F053Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 PRTR-C17.I1open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2076242026-06-13T07:49:27Z
score 15,812429

Similares en LA Referencia