Catalytic Transformations of Functionalized Cyclic Organic Carbonates

Functionalized cyclic organic carbonates and related heterocycles have emerged as highly versatile heterocyclic substrates for ring-opening and decarboxylative catalytic transformations allowing for the development of new stereo- and enantioselective C‒N, C‒O, C‒C, C-S and C‒B bond formation reactio...

Descripción completa

Detalles Bibliográficos
Autores: Guo, Wusheng, Gómez, José Enrique, Cristòfol, Àlex, Xie, Jianing, Kleij, Arjan W.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/356064
Acceso en línea:http://hdl.handle.net/2072/356064
https://doi.org/10.1002/anie.201805009
Access Level:acceso abierto
Palabra clave:54
Descripción
Sumario:Functionalized cyclic organic carbonates and related heterocycles have emerged as highly versatile heterocyclic substrates for ring-opening and decarboxylative catalytic transformations allowing for the development of new stereo- and enantioselective C‒N, C‒O, C‒C, C-S and C‒B bond formation reactions. Transition metal mediated conversions have only recently been rejuvenated as powerful approaches towards the preparation of more complex molecules. This minireview will highlight the potential of cyclic carbonates and structurally related heterocycles with a focus on their synthetic value and the mechanistic manifolds that are involved upon their conversion.