Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks

Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have aw...

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Autores: Khobotov-Bakishev, Akim, Hernández-López, Laura, Baeckmann, Cornelia von, Albalad, Jorge, Carné-Sánchez, Arnau, Maspoch, Daniel
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/289523
Acesso em linha:http://hdl.handle.net/10261/289523
Access Level:acceso abierto
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spelling Metal-Organic Polyhedra as Building Blocks for Porous Extended NetworksKhobotov-Bakishev, AkimHernández-López, LauraBaeckmann, Cornelia vonAlbalad, JorgeCarné-Sánchez, ArnauMaspoch, DanielMetal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.A.K.-B. and L.H.-L. contributed equally to this work. This work was supported by the Spanish MINECO (project RTI2018-095622-B-I00) and the Catalan AGAUR (project 2017 SGR 238). L.H.-L. acknowledges the support from the Spanish State Research Agency (PRE2019-088056). It was also funded by the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from the Spanish MINECO (Grant No. SEV-2017-0706). The project that gave rise to these results received the support of a fellowship (LCF/BQ/PR20/11770011) from “La Caixa” Foundation (ID 100010434).Wiley-VCHMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)Generalitat de CatalunyaLa CaixaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2023202320222023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_dcae04bcPublisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/289523reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095622-B-I00info:eu-repo/grantAgreement/AEI//PRE2019-088056info:eu-repo/grantAgreement/AEI//SEV-2017-0706http://dx.doi.org/10.1002/advs.202104753Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2895232026-05-22T06:33:51Z
dc.title.none.fl_str_mv Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
title Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
spellingShingle Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
Khobotov-Bakishev, Akim
title_short Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
title_full Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
title_fullStr Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
title_full_unstemmed Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
title_sort Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
dc.creator.none.fl_str_mv Khobotov-Bakishev, Akim
Hernández-López, Laura
Baeckmann, Cornelia von
Albalad, Jorge
Carné-Sánchez, Arnau
Maspoch, Daniel
author Khobotov-Bakishev, Akim
author_facet Khobotov-Bakishev, Akim
Hernández-López, Laura
Baeckmann, Cornelia von
Albalad, Jorge
Carné-Sánchez, Arnau
Maspoch, Daniel
author_role author
author2 Hernández-López, Laura
Baeckmann, Cornelia von
Albalad, Jorge
Carné-Sánchez, Arnau
Maspoch, Daniel
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
Generalitat de Catalunya
La Caixa
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_dcae04bc
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/289523
url http://hdl.handle.net/10261/289523
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095622-B-I00
info:eu-repo/grantAgreement/AEI//PRE2019-088056
info:eu-repo/grantAgreement/AEI//SEV-2017-0706
http://dx.doi.org/10.1002/advs.202104753
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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