Predicting the self-assembly of superparamagnetic colloids under magnetic fields

Self-assembly processes are very important in material sciences but are particularly difficult to predict quantitatively. This is the case for particulate magnetic materials in which field-induced self-assembly processes are essential. This article describes the recent advances in the development of...

Descripción completa

Detalles Bibliográficos
Autores: Faraudo, Jordi|||0000-0002-6315-4993, Andreu Segura, Jordi, Calero, Carlos|||0000-0002-1977-1724, Camacho, Juan|||0000-0002-8095-4167
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:304146
Acceso en línea:https://ddd.uab.cat/record/304146
https://dx.doi.org/urn:doi:10.1002/adfm.201504839
Access Level:acceso abierto
Palabra clave:Colloidal materials
Magnetic field directed self-assembly
Superparamagnetism
Theory and simulation
Thermodynamics of self-assembly
Descripción
Sumario:Self-assembly processes are very important in material sciences but are particularly difficult to predict quantitatively. This is the case for particulate magnetic materials in which field-induced self-assembly processes are essential. This article describes the recent advances in the development of predictive theoretical tools for the study of directed self-assembly of superparamagnetic colloids under magnetic fields. A practical view is presented of how to employ the new concepts (derived from thermodynamic theory) to predict the possible assembled structures from the properties of the colloids and thermodynamic conditions. Quantitative prediction of kinetics is also discussed for the cases in which equilibrium theory is not relevant. Finally, an outline of fundamental aspects of the theory is presented.