uadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) have been prepared and structurally characterized. The steric hindrance exerted by the Ar Xyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a for...

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Detalles Bibliográficos
Autores: Carrasco, Mario, Faust, Michelle, Peloso, Riccardo, Rodríguez, Amor, López-Serrano, Joaquín, Álvarez, Eleuterio, Maya, Celia, Power, Philip P., Carmona, Ernesto
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/96025
Acceso en línea:http://hdl.handle.net/10261/96025
Access Level:acceso abierto
Descripción
Sumario:New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) have been prepared and structurally characterized. The steric hindrance exerted by the Ar Xyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a formal fourteen-electron count. © 2012 The Royal Society of Chemistry