Interrogating the CISS effect in chiral and paramagnetic organic radicals
Continuous research on new chiral molecular materials brings new exciting properties to the field of molecular electronics. The discovery of the chirality-induced spin selectivity (CISS) effect has expanded the list of applications for chiral structures, opening promising avenues for their exploitat...
| Autores: | , , , , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:302033 |
| Acceso en línea: | https://ddd.uab.cat/record/302033 https://dx.doi.org/urn:doi:10.1039/d4tc01389a |
| Access Level: | acceso abierto |
| Palabra clave: | Chiral structures Functionalized Molecular materials Molecular spins Molecular spintronics Organic radicals Organics Property Selectivity effects Spin-polarization |
| Sumario: | Continuous research on new chiral molecular materials brings new exciting properties to the field of molecular electronics. The discovery of the chirality-induced spin selectivity (CISS) effect has expanded the list of applications for chiral structures, opening promising avenues for their exploitation in molecular spintronics. In this work, the persistent propeller-like organic perchlorotriphenylmethyl (PTM) radical is investigated as a potential spin filter combining chirality and paramagnetism. In particular, two different PTM derivatives, mono- and bis-functionalized, with one or two terminal alkyne groups have been used for the preparation of enantioenriched solid-state assemblies. The analysis of their chiroptical properties reveals that the functionalization does not play a crucial role in their final conformational stability and highlights the dissimilarities of the racemization barriers in solution and solid states. Spin-dependent electrochemical and charge transport measurements of enantioenriched PTM-based self-assembled monolayers did not reveal the existence of the CISS effect. Density functional theory quantum transport calculations show that the most dominant contribution to the spin polarization would not be CISS-related polarization, but the one intrinsically associated with the radical spin. Nevertheless, at room temperature this contribution is affected by thermal fluctuations averaging to a net zero spin polarization. |
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