Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners

[EN] The present work aims to develop thermosetting resins using epoxidized hemp oil (EHO) as a bio-based epoxy matrix and a mixture of methyl nadic anhydride (MNA) and maleinized hemp oil (MHO) in different ratios as hardeners. The results show that the mixture with only MNA as a hardener is charac...

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Authors: Lerma-Canto, Alejandro, Samper, María-Dolores|||0000-0002-5102-8412, Domínguez-Candela, Iván|||0000-0003-3288-1079, Garcia-Garcia, Daniel|||0000-0002-2520-0186, Fombuena, Vicent|||0000-0001-7266-6205
Format: article
Publication Date:2023
Country:España
Institution:Universitat Politècnica de València (UPV)
Repository:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Language:English
OAI Identifier:oai:riunet.upv.es:10251/202766
Online Access:https://riunet.upv.es/handle/10251/202766
Access Level:Open access
Keyword:Epoxidized hemp seed oil
Vegetable oils
Crosslinking
Cyclic anhydrides
INGENIERIA QUIMICA
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
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oai_identifier_str oai:riunet.upv.es:10251/202766
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
title Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
spellingShingle Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
Lerma-Canto, Alejandro
Epoxidized hemp seed oil
Vegetable oils
Crosslinking
Cyclic anhydrides
INGENIERIA QUIMICA
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
title_short Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
title_full Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
title_fullStr Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
title_full_unstemmed Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
title_sort Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride Hardeners
dc.creator.none.fl_str_mv Lerma-Canto, Alejandro
Samper, María-Dolores|||0000-0002-5102-8412
Domínguez-Candela, Iván|||0000-0003-3288-1079
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Fombuena, Vicent|||0000-0001-7266-6205
author Lerma-Canto, Alejandro
author_facet Lerma-Canto, Alejandro
Samper, María-Dolores|||0000-0002-5102-8412
Domínguez-Candela, Iván|||0000-0003-3288-1079
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Fombuena, Vicent|||0000-0001-7266-6205
author_role author
author2 Samper, María-Dolores|||0000-0002-5102-8412
Domínguez-Candela, Iván|||0000-0003-3288-1079
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Fombuena, Vicent|||0000-0001-7266-6205
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Química y Nuclear
Departamento de Ingeniería Mecánica y de Materiales
Instituto Universitario de Seguridad Industrial, Radiofísica y Medioambiental
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
European Commission
Generalitat Valenciana
Agencia Estatal de Investigación
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Epoxidized hemp seed oil
Vegetable oils
Crosslinking
Cyclic anhydrides
INGENIERIA QUIMICA
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
topic Epoxidized hemp seed oil
Vegetable oils
Crosslinking
Cyclic anhydrides
INGENIERIA QUIMICA
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
description [EN] The present work aims to develop thermosetting resins using epoxidized hemp oil (EHO) as a bio-based epoxy matrix and a mixture of methyl nadic anhydride (MNA) and maleinized hemp oil (MHO) in different ratios as hardeners. The results show that the mixture with only MNA as a hardener is characterized by high stiffness and brittleness. In addition, this material is characterized by a high curing time of around 170 min. On the other hand, as the MHO content in the resin increases, the mechanical strength properties decrease and the ductile properties increase. Therefore, it can be stated that the presence of MHO confers flexible properties to the mixtures. In this case, it was determined that the thermosetting resin with balanced properties and high bio-based content contains 25% MHO and 75% MNA. Specifically, this mixture obtained a 180% higher impact energy absorption and a 195% lower Young's modulus than the sample with 100% MNA. Also, it has been observed that this mixture has significantly shorter times than the mixture containing 100% MNA (around 78 min), which is of great concern at an industrial level. Therefore, thermosetting resins with different mechanical and thermal properties can be obtained by varying the MHO and MNA content.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-03-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/202766
url https://riunet.upv.es/handle/10251/202766
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-119142RA-I00 EVAPORACION NATURAL ASISTIDA CON MATERIALES ABSORBENTES DE BAJO COSTE PARA EL TRATAMIENTO DE EFLUENTES CONCENTRADOS DE GESTION COMPLEJA
Universitat Politècnica de València https://doi.org/10.13039/501100004233 SP20190013
Generalitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2020%2F233
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 TED2021-129920A-C43
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 TED2021-131762A-I00
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Epoxidized and Maleinized Hemp Oil to Develop Fully Bio-Based Epoxy Resin Based on Anhydride HardenersLerma-Canto, AlejandroSamper, María-Dolores|||0000-0002-5102-8412Domínguez-Candela, Iván|||0000-0003-3288-1079Garcia-Garcia, Daniel|||0000-0002-2520-0186Fombuena, Vicent|||0000-0001-7266-6205Epoxidized hemp seed oilVegetable oilsCrosslinkingCyclic anhydridesINGENIERIA QUIMICACIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA08.- Fomentar el crecimiento económico sostenido, inclusivo y sostenible, el empleo pleno y productivo, y el trabajo decente para todos09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación[EN] The present work aims to develop thermosetting resins using epoxidized hemp oil (EHO) as a bio-based epoxy matrix and a mixture of methyl nadic anhydride (MNA) and maleinized hemp oil (MHO) in different ratios as hardeners. The results show that the mixture with only MNA as a hardener is characterized by high stiffness and brittleness. In addition, this material is characterized by a high curing time of around 170 min. On the other hand, as the MHO content in the resin increases, the mechanical strength properties decrease and the ductile properties increase. Therefore, it can be stated that the presence of MHO confers flexible properties to the mixtures. In this case, it was determined that the thermosetting resin with balanced properties and high bio-based content contains 25% MHO and 75% MNA. Specifically, this mixture obtained a 180% higher impact energy absorption and a 195% lower Young's modulus than the sample with 100% MNA. Also, it has been observed that this mixture has significantly shorter times than the mixture containing 100% MNA (around 78 min), which is of great concern at an industrial level. Therefore, thermosetting resins with different mechanical and thermal properties can be obtained by varying the MHO and MNA content.This research was funded by MCIN/AEI/ 10.13039/501100011033 through the PID-AEI Project (grants PID2020-119142RA-I00 and PID2021-123753NA-C33) and the TED-AEI Project (grants TED2021-129920A-C43 and TED2021-131762A-100) and, as appropriate, by ¿ERDF A way of making Europe¿, by the ¿European Union¿ or by the ¿European Union NextGenerationEU/PRTR¿. Dominguez-Candela wants to thank Universitat Politècnica de València for his FPI grant (PAID-2019-SP20190013) and Generalitat Valenciana (GVA) for his FPI grant (ACIF/2020/233).MDPI AGDepartamento de Ingeniería Química y NuclearDepartamento de Ingeniería Mecánica y de MaterialesInstituto Universitario de Seguridad Industrial, Radiofísica y Medioambiental Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyEuropean CommissionGeneralitat ValencianaAgencia Estatal de InvestigaciónUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20232023-03-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/202766reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-119142RA-I00 EVAPORACION NATURAL ASISTIDA CON MATERIALES ABSORBENTES DE BAJO COSTE PARA EL TRATAMIENTO DE EFLUENTES CONCENTRADOS DE GESTION COMPLEJAUniversitat Politècnica de València https://doi.org/10.13039/501100004233 SP20190013Generalitat Valenciana https://doi.org/10.13039/501100003359 ACIF%2F2020%2F233Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 TED2021-129920A-C43Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 TED2021-131762A-I00open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2027662026-06-13T07:49:27Z
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