Photochemical incorporation of N-benzylidene(phenyl)amine into the complex [{Ti(η5-C5Me5)(η-O)}3(μ3-CH)] as a model of the titanium oxide surface

The photochemical incorporation of PhCHNNPh to the metal oxide model [{TiCp*(m-O)}3(m3-CH)] (Cp* = h5-C5Me5) occurs by breaking of the CNN imine bond and formation of m-imido and sigma-alkenyl groups on the [Ti3O3] core; the crystal structure of the obtained product, [{TiCp*(m-O)}3(m-NPh)(CHNCHPh)],...

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Detalhes bibliográficos
Autores: Gómez Sal, Pilar|||0000-0002-9279-210X, Martín Alonso, Avelino|||0000-0002-9776-9670, Mena Montoro, Miguel|||0000-0001-7456-1212, Morales Varela, María del Carmen, Santamaría Angulo, Cristina|||0000-0003-2410-961X
Formato: artículo
Fecha de publicación:1999
País:España
Recursos:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/63085
Acesso em linha:http://hdl.handle.net/10017/63085
https://dx.doi.org/10.1039/A905129E
Access Level:acceso abierto
Palavra-chave:Química
Chemistry
Descrição
Resumo:The photochemical incorporation of PhCHNNPh to the metal oxide model [{TiCp*(m-O)}3(m3-CH)] (Cp* = h5-C5Me5) occurs by breaking of the CNN imine bond and formation of m-imido and sigma-alkenyl groups on the [Ti3O3] core; the crystal structure of the obtained product, [{TiCp*(m-O)}3(m-NPh)(CHNCHPh)], was determined by Xray diffraction.

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