A theoretical study of the structure of 6,6-dimethyl-7-nitroso-4,5,6, 7-tetrahydro-1H-pyrazolo[3,4-b]pyridine

DFT calculations have been carried out on 6,6-dimethyl-7-nitroso-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-ö]pyridine concerning energies, absolute shieldings (GIAO) and molecular graphs (AIM) to determine the molecular structure of the compound (tautomerism and conformation of the nitroso group).

Detalles Bibliográficos
Autores: Echevarría, A, Alkorta, Ibon, Elguero, José
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/153983
Acceso en línea:http://hdl.handle.net/10261/153983
Access Level:acceso abierto
Palabra clave:Aminopyrazoles
DFT calculations
Rearrangement
NMR
Pyrazolo[3,4-b]pyridines
Descripción
Sumario:DFT calculations have been carried out on 6,6-dimethyl-7-nitroso-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-ö]pyridine concerning energies, absolute shieldings (GIAO) and molecular graphs (AIM) to determine the molecular structure of the compound (tautomerism and conformation of the nitroso group).