Power cycles integration in concentrated solar power plants with energy storage based on calcium looping

Efficient, low-cost and environmentally friendly storage of thermal energy stands as a main challenge for large scale deployment of solar energy. This work explores the integration into concentrated solar power plants of the calcium looping process based upon the reversible carbonation/calcination o...

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Detalles Bibliográficos
Autores: Ortiz Domínguez, Carlos, Chacartegui, Ricardo, Valverde Millán, José Manuel, Alovisio, A., Becerra Villanueva, José Antonio
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2017
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/69843
Acceso en línea:https://hdl.handle.net/11441/69843
https://doi.org/10.1016/j.enconman.2017.03.029
Access Level:acceso abierto
Palabra clave:Calcium Looping (CaL)
Concentrated Solar Power (CSP)
Global warming
Power cycles
Renewable energies
Supercritical CO2 power cycle
Thermochemical Energy Storage (TCES)
Descripción
Sumario:Efficient, low-cost and environmentally friendly storage of thermal energy stands as a main challenge for large scale deployment of solar energy. This work explores the integration into concentrated solar power plants of the calcium looping process based upon the reversible carbonation/calcination of calcium oxide for thermochemical energy storage. An efficient concentrated solar power-calcium looping integration would allow storing energy in the long term by calcination of calcium carbonate thus overcoming the hurdle of variable power generation from solar. After calcination, the stored products of the reaction (calcium oxide and carbon dioxide) are brought together in a carbonator reactor whereby the high temperature exothermic reaction releases the stored energy for efficient power production when needed. This work analyses several power cycle configurations with the main goal of optimizing the performance of the overall system integration. Possible integration schemes are proposed in which power production is carried out directly (using a closed carbon dioxide Brayton power cycle) or indirectly (by means of a steam reheat Rankine cycle or a supercritical carbon dioxide Brayton cycle). The results obtained show that the highest plant efficiencies (up to 45–46%) are achievable using a closed carbon dioxide Brayton power cycle.