Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes

Tesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química Orgánica. Fecha de lectura: 04-09-2020

Detalhes bibliográficos
Autor: Mena Hernando, Sofía
Formato: tesis doctoral
Fecha de publicación:2020
País:España
Recursos:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/695320
Acesso em linha:http://hdl.handle.net/10486/695320
Access Level:acceso abierto
Palavra-chave:Polímeros
Nanotubos
Compuestos organometálicos
Química
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spelling Molecular Machines and Materials Based on Mechanically Interlocked Carbon NanotubesMáquinas moleculares y Materiales basados en Nanotubos de Carbono Mecánicamente EntrelazadosMena Hernando, SofíaPolímerosNanotubosCompuestos organometálicosQuímicaTesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química Orgánica. Fecha de lectura: 04-09-2020A mechanical bond presents a combination of the best features of covalent and supramolecular chemistries (stability and structural integrity), plus a unique dynamic nature, that makes it a very interesting tool for materials chemistry. This doctoral thesis examines the chemistry of the mechanical bond applied to polymers, single-walled carbon nanotubes (SWNTs), metal–organic frameworks (MOFs) and mechanical interlocked molecules (MIMs). The first chapter comprises an introduction regarding several synthetic strategies towards polycatenanes and polyrotaxanes, considering their potential impact in polymer chemistry. This is exemplified by their use in stimuli-responsive gels and as binders in battery electrodes. Subsequently, it is shown how to include mechanically interlocked components in MOFs, along with the distinctive dynamic properties of the structures achieved. Likewise, tackling some of the classic problems of SWNTs is intended through the introduction of the mechanical linkage, accomplishing mechanically interlocked single-walled carbon nanotubes (MINTs). The following chapters of this work are focused on the experimental use of the mechanical bond as a toolkit towards the manufacture of MINTs-based polymer composites (chapter 2), as well as the applicability of its dynamic features in MOFs (chapter 3). Nevertheless, the main chapter of this thesis is dedicated to the organic synthesis of daisy chains (chapter 4), an example of MIMs which can lead to particularly attractive molecular machines. Conclusively, a collaborative final chapter (not related to the use of mechanical bonding) entails the synthesis of covalent organic frameworks (COFs) bearing pyrene molecules (chapter 5). These solid-state structures show highly promising applications in chemical sensing of pollutants directly in water. Along these lines, a little circle around some modern chemical architectures is eventually depicted, aiming to endorse the design of up-to-date machinery in materials sciencePérez Álvarez, Emilio ManuelDepartamento de Química OrgánicaFacultad de CienciasInstituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanociencia)20202020-09-24doctoral thesishttp://purl.org/coar/resource_type/c_db06NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/doctoralThesisapplication/pdfhttp://hdl.handle.net/10486/695320reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6953202026-06-23T12:46:27Z
dc.title.none.fl_str_mv Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
Máquinas moleculares y Materiales basados en Nanotubos de Carbono Mecánicamente Entrelazados
title Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
spellingShingle Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
Mena Hernando, Sofía
Polímeros
Nanotubos
Compuestos organometálicos
Química
title_short Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
title_full Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
title_fullStr Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
title_full_unstemmed Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
title_sort Molecular Machines and Materials Based on Mechanically Interlocked Carbon Nanotubes
dc.creator.none.fl_str_mv Mena Hernando, Sofía
author Mena Hernando, Sofía
author_facet Mena Hernando, Sofía
author_role author
dc.contributor.none.fl_str_mv Pérez Álvarez, Emilio Manuel
Departamento de Química Orgánica
Facultad de Ciencias
Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanociencia)
dc.subject.none.fl_str_mv Polímeros
Nanotubos
Compuestos organometálicos
Química
topic Polímeros
Nanotubos
Compuestos organometálicos
Química
description Tesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química Orgánica. Fecha de lectura: 04-09-2020
publishDate 2020
dc.date.none.fl_str_mv 2020
2020-09-24
dc.type.none.fl_str_mv doctoral thesis
http://purl.org/coar/resource_type/c_db06
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/695320
url http://hdl.handle.net/10486/695320
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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