Effect of olive-pruning fibres as reinforcements of alkali-activated cements based on electric arc furnace slag and biomass bottom ash
In this work, alkali-activated composites using electric arc furnace slag (50 wt%) and biomass bottom ash (50 wt%) were manufactured, adding olive-pruning fibres as reinforcement. The objective of adding fibres is to improve the flexural strength of composites, as well as to prevent the expansion of...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Universidad de Jaén |
| Repositorio: | RUJA. Repositorio Institucional de la Producción Científica de la Universidad de Jaén |
| OAI Identifier: | oai:ruja.ujaen.es:10953/6101 |
| Acceso en línea: | https://link.springer.com/article/10.1007/s43452-024-00882-0#Fun https://hdl.handle.net/10953/6101 |
| Access Level: | acceso abierto |
| Palabra clave: | Alkali-activated cements Fibre treatment Natural fibres Electric arc furnace slag Biomass bottom ash 69 |
| Sumario: | In this work, alkali-activated composites using electric arc furnace slag (50 wt%) and biomass bottom ash (50 wt%) were manufactured, adding olive-pruning fibres as reinforcement. The objective of adding fibres is to improve the flexural strength of composites, as well as to prevent the expansion of cracks as a result of shrinkage. For this reason, composites reinforced with olive-pruning fibres (0.5–2 wt%) untreated and treated with three different solutions to improve matrix–fibre adhesion were manufactured. Treatments developed over fibres were a 10 wt% Na2SiO3 solution, 3 wt% CaCl2 solution and 5 wt% NaOH solution. Mechanical properties, physical properties, thermal properties and the microstructure of composites by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) were studied to demonstrate the improvement. Alkaline treatment degraded fibre surface, increasing the matrix–fibre adhesion, and as a consequence, flexural strength increased up to 20% at 90 days of curing. Optimal results were obtained with composites reinforced with 1 wt% of olive-pruning fibre treated by a 10 wt% Na2SiO3 solution. Higher quantity of olive-pruning fibre leads to local agglomeration, which weakens the matrix–fibre adhesion. The effect on the compressive strength is less evident, since the addition of fibres produces an admissible decrease (between 0 and 9% using 0.5 or 1 wt% of fibres), except in composites that use olive pruning treated with 10 wt% Na2SiO3 solution, where values remain stable, similar or better to control paste. A greater ductility of the matrix in all composites was observed. Furthermore, the alkali-activated cement matrix was bonded to olive-pruning fibre better than untreated fibre, as it is shown in SEM images. Thus, the results showed that olive-pruning fibres could be used as reinforcement in the manufacturing of alkali-activated materials when they are treated with alkali solutions. |
|---|