Microwave-assisted synthesis and characterization of new cathodic material for solid oxide fuel cells: La0.3Ca0.7Fe0.7Cr0.3O3−d
In this work, we examine the benefits of alternative powder processing methods, with a primary focus on microwave-based synthesis, that could both lower material manufacturing costs and further enhance cathode performance for solid oxide fuel cell applications. La0.3Ca0.7Fe0.7Cr0.3O3−δ (LCFCr), form...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/92290 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/92290 |
| Access Level: | acceso abierto |
| Palabra clave: | 546 Microwave synthesis SOFCs Química inorgánica (Química) 2303 Química Inorgánica 2210.28 Química del Estado Sólido |
| Sumario: | In this work, we examine the benefits of alternative powder processing methods, with a primary focus on microwave-based synthesis, that could both lower material manufacturing costs and further enhance cathode performance for solid oxide fuel cell applications. La0.3Ca0.7Fe0.7Cr0.3O3−δ (LCFCr), formed using conventional solid-state methods, has been shown in earlier work to be a very promising catalyst for the oxygen reduction reaction. To further increase its performance, microwave methods were used to increase the surface area of LCFCr and to decrease the synthesis time. It was found that the material could be obtained in crystalline form in only 7 h, with the synthesis temperature lowered by roughly 300 °C as compared to conventional methods. |
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