Graphene nanoplatelets for electrically conductive 3YTZP composites densified by pressureless sintering

3 mol% yttria tetragonal zirconia polycrystalline (3YTZP) ceramic composites with 2.5, 5 and 10 vol% graphene nanoplatelets (GNP) were pressureless sintered in argon atmosphere between 1350 and 1450 °C. The effects of the GNP content and the sintering temperature on the densification, microstructure...

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Detalles Bibliográficos
Autores: López Pernía, Cristina, Gallardo López, Ángela María, Morales Rodríguez, Ana, Poyato Galán, Rosalía
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2019
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/142596
Acceso en línea:https://hdl.handle.net/11441/142596
https://doi.org/10.1016/j.jeurceramsoc.2019.05.067
Access Level:acceso abierto
Palabra clave:Electrical properties
Graphene nanoplatelet
Pressureless sintering
Zirconia
Descripción
Sumario:3 mol% yttria tetragonal zirconia polycrystalline (3YTZP) ceramic composites with 2.5, 5 and 10 vol% graphene nanoplatelets (GNP) were pressureless sintered in argon atmosphere between 1350 and 1450 °C. The effects of the GNP content and the sintering temperature on the densification, microstructure and electrical properties of the composites were investigated. An isotropic distribution of GNP surrounding ceramic regions was exhibited regardless the GNP content and sintering temperature used. Electrical conductivity values comparable to the ones of fully dense composites prepared by more complex techniques were obtained, even though full densification was not achieved. While the composite with 5 vol% GNP exhibited electrical anisotropy with a semiconductor-type behaviour, the composite with 10 vol% GNP showed an electrically isotropic metallic-type behaviour.