Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions
7 páginas, 4 figuras, 3 tablas.
| Autores: | , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2009 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/37036 |
| Acceso en línea: | http://hdl.handle.net/10261/37036 |
| Access Level: | acceso abierto |
| Palabra clave: | Trinuclear coper Crystal structures Trinuclear complexes Ullman Sonogashira |
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oai:digital.csic.es:10261/37036 |
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España |
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Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactionsBiffis, AndreaTubaro, CristinaScattolin, ElenaBasato, MarinoPapini, GraziaSantini, CarloÁlvarez, EleuterioConejero, SalvadorTrinuclear coperCrystal structuresTrinuclear complexesUllmanSonogashira7 páginas, 4 figuras, 3 tablas.Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.This work was partially supported by MIUR (PRIN 2006038447 and PRIN 20078EWK9B), by Consolider-Ingenio 2010 (No. CSD2007-00006) (FEDER support) and by the Junta de Andalucia (Project No. FQM-3151).Peer reviewedRoyal Society of Chemistry (UK)201120112009info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://hdl.handle.net/10261/37036reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1039/B906730Binfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/370362026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| title |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| spellingShingle |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions Biffis, Andrea Trinuclear coper Crystal structures Trinuclear complexes Ullman Sonogashira |
| title_short |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| title_full |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| title_fullStr |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| title_full_unstemmed |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| title_sort |
Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions |
| dc.creator.none.fl_str_mv |
Biffis, Andrea Tubaro, Cristina Scattolin, Elena Basato, Marino Papini, Grazia Santini, Carlo Álvarez, Eleuterio Conejero, Salvador |
| author |
Biffis, Andrea |
| author_facet |
Biffis, Andrea Tubaro, Cristina Scattolin, Elena Basato, Marino Papini, Grazia Santini, Carlo Álvarez, Eleuterio Conejero, Salvador |
| author_role |
author |
| author2 |
Tubaro, Cristina Scattolin, Elena Basato, Marino Papini, Grazia Santini, Carlo Álvarez, Eleuterio Conejero, Salvador |
| author2_role |
author author author author author author author |
| dc.subject.none.fl_str_mv |
Trinuclear coper Crystal structures Trinuclear complexes Ullman Sonogashira |
| topic |
Trinuclear coper Crystal structures Trinuclear complexes Ullman Sonogashira |
| description |
7 páginas, 4 figuras, 3 tablas. |
| publishDate |
2009 |
| dc.date.none.fl_str_mv |
2009 2011 2011 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/37036 |
| url |
http://hdl.handle.net/10261/37036 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
http://dx.doi.org/10.1039/B906730B |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Royal Society of Chemistry (UK) |
| publisher.none.fl_str_mv |
Royal Society of Chemistry (UK) |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
| instname_str |
Consejo Superior de Investigaciones Científicas (CSIC) |
| reponame_str |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| collection |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
|
| _version_ |
1869410390551560192 |
| score |
15.811543 |