Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry

Producción Científica

Detalles Bibliográficos
Autores: De La Fuente Ballesteros, Adrián, Brugnerotto, Patricia, Costa, Ana C.O., Nozal Nalda, María Jesús del, Ares Sacristán, Ana María, Bernal del Nozal, José
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/64393
Acceso en línea:https://doi.org/10.1016/j.foodchem.2022.135245
https://uvadoc.uva.es/handle/10324/64393
Access Level:acceso abierto
Palabra clave:Acaricides
Food analysis
Food safety
Gas chromatography-mass spectrometry
Honey
Method validation
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spelling Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometryDe La Fuente Ballesteros, AdriánBrugnerotto, PatriciaCosta, Ana C.O.Nozal Nalda, María Jesús delAres Sacristán, Ana MaríaBernal del Nozal, JoséAcaricidesFood analysisFood safetyGas chromatography-mass spectrometryHoneyMethod validationProducción CientíficaAn analytical method has been proposed and validated to determine seven acaricides (atrazine, chlorpyrifos, chlorfenvinphos, α-endosulfan, bromopropylate, coumaphos, and τ-fluvalinate) in honeys from different botanical origins (multifloral, heather and rosemary) by means of gas chromatography-mass spectrometry. An efficient and simple sample treatment was proposed that involved a solvent extraction with an ethyl acetate and cyclohexane (50:50, v/v) mixture. Chromatographic analysis (<25 min) was performed in a DB-5MS column under programmed temperature conditions. The method was validated in terms of selectivity, limits of detection (0.2–2.0 μg kg-1) and quantification (0.5–7.6 μg kg-1), linearity (limit of quantification-700 (heather) or 800 (multifloral and rosemary) μg kg-1), matrix effect (<20 % in most cases), trueness (recoveries between 81 % and 108 %), and precision (relative standard deviation < 15 %). Finally, of the seven acaricides investigated in several honey samples only τ-fluvalinate residues (<limit of quantification - 23 μg kg-1) were found.Este trabajo forma parte del proyecto de investigación financiado por el Ministerio de Economía y Competitividad e INIA-FEDER (RTA2017-00004-C02-02).Elsevier2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://doi.org/10.1016/j.foodchem.2022.135245https://uvadoc.uva.es/handle/10324/64393reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://www.sciencedirect.com/science/article/pii/S0308814622032071?via%3Dihubinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/643932026-06-13T12:44:47Z
dc.title.none.fl_str_mv Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
title Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
spellingShingle Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
De La Fuente Ballesteros, Adrián
Acaricides
Food analysis
Food safety
Gas chromatography-mass spectrometry
Honey
Method validation
title_short Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
title_full Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
title_fullStr Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
title_full_unstemmed Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
title_sort Determination of acaricides in honeys from different botanical origins by gas chromatography-mass spectrometry
dc.creator.none.fl_str_mv De La Fuente Ballesteros, Adrián
Brugnerotto, Patricia
Costa, Ana C.O.
Nozal Nalda, María Jesús del
Ares Sacristán, Ana María
Bernal del Nozal, José
author De La Fuente Ballesteros, Adrián
author_facet De La Fuente Ballesteros, Adrián
Brugnerotto, Patricia
Costa, Ana C.O.
Nozal Nalda, María Jesús del
Ares Sacristán, Ana María
Bernal del Nozal, José
author_role author
author2 Brugnerotto, Patricia
Costa, Ana C.O.
Nozal Nalda, María Jesús del
Ares Sacristán, Ana María
Bernal del Nozal, José
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Acaricides
Food analysis
Food safety
Gas chromatography-mass spectrometry
Honey
Method validation
topic Acaricides
Food analysis
Food safety
Gas chromatography-mass spectrometry
Honey
Method validation
description Producción Científica
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1016/j.foodchem.2022.135245
https://uvadoc.uva.es/handle/10324/64393
url https://doi.org/10.1016/j.foodchem.2022.135245
https://uvadoc.uva.es/handle/10324/64393
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://www.sciencedirect.com/science/article/pii/S0308814622032071?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,198674

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