Is ozone production able to explain the good performance of CabECO® technology in wastewater treatment?

This work intends to go a step further in the application of electrochemical technology to produce ozone, by evaluating the production of ozone with a commercial cell registered as CabECO®, which has been previously used to disinfect heavily polluted water in a successful manner, with a view to asce...

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Bibliographic Details
Authors: Rodriguez-Peña, Mayra, Barrios, José Antonio, Llanos López, Javier, Sáez Jiménez, Cristina, Barrera-Díaz, Carlos Eduardo, Rodrigo Rodrigo, Manuel Andrés
Format: article
Publication Date:2021
Country:España
Institution:Universidad de Castilla-La Mancha
Repository:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/29439
Online Access:https://doi.org/10.1016/j.electacta.2021.139262
http://hdl.handle.net/10578/29439
Access Level:Open access
Keyword:CabECO® technology
Electro-ozonizers
Temperature regulation
Ozone production
Description
Summary:This work intends to go a step further in the application of electrochemical technology to produce ozone, by evaluating the production of ozone with a commercial cell registered as CabECO®, which has been previously used to disinfect heavily polluted water in a successful manner, with a view to ascertaining whether this success may be related to the production of ozone. The CabECO® cell is a PEM electrolyzer; that is to say, one in which anode and cathode are connected through a PEM membrane. Since ozone production on the electrolyte is important and depends on the composition of the liquid, attention must be paid to the electrochemical production of scavengers. Dosing of oxygen as microbubbles has a very positive effect on the production of ozone, while temperature regulation is as well considerably important, as the increase in temperature generated by ohmic losses can lead to important decreases in the efficiency of ozone electrogeneration. Rates within the range 0.06–0.60 mg O3 min−1 are observed; this means that the maximum current efficiency reached is as high as 6.11% (considering oxygen as raw matter). These results are extremely promising as compared with other references in the literature, at once they also indicate there is room for further improvements and a long way to prevent the effect of scavengers and increase the efficiency of the process.