Energy-efficient electro-ozonizers: A solution for antibiotic-resistant bacteria (ARB) in wastewater

This study evaluates the energetic aspects and competitiveness of Proton Exchange Membrane (PEM) technology for the electrochemical generation of ozone gas, used as a disinfectant for pretreating hospital wastewater to reduce bacterial load. The findings indicate that higher current densities favor...

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Detalhes bibliográficos
Autores: Correia Alonso, Sergio Enmanuel, Lacasa Fernández, Engracia, Cañizares Cañizares, Pablo, Rodrigo Rodrigo, Manuel Andrés, Sáez Jiménez, Cristina
Tipo de documento: artigo
Data de publicação:2025
País:España
Recursos:Universidad de Castilla-La Mancha
Repositório:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/47753
Acesso em linha:https://doi.org/10.1016/j.psep.2025.107639
https://hdl.handle.net/10578/47753
Access Level:Acceso aberto
Palavra-chave:Antibiotic-resistant bacteria
Disinfection
PEM cell
Ozone
Hospital wastewater
Descrição
Resumo:This study evaluates the energetic aspects and competitiveness of Proton Exchange Membrane (PEM) technology for the electrochemical generation of ozone gas, used as a disinfectant for pretreating hospital wastewater to reduce bacterial load. The findings indicate that higher current densities favor the efficiency of ozone production over oxygen evolution, with energy consumption values ranging from 0.38 to 0.86 kWh per gram of O3 at current densities of 75 and 25 mA cm⁻², respectively. PEM technology demonstrates high effectiveness and competitiveness in reducing bacterial load in hospital effluents compared to other Advanced Oxidation Processes (AOPs). The use of a jet aerator significantly enhances process efficiency, achieving up to a tenfold increase compared to non-aerated conditions, and with energy consumption values of 2.37 and 1.16 kWh per cubic meter per order at suction flow rates of 0.1 and 0.4 L min⁻¹ , respectively. In continuous operation mode, the flow rate of treated urine impacts the inactivation of K. pneumoniae, with disinfection rates exceeding 99.99 % achieved at flow rates below 0.250 L h⁻¹ and ratios of g O₃ per g DOC above 0.05. These findings underscore the potential of PEM technology as an efficient and competitive method for hospital wastewater disinfection.