C, Cl and H compound-specific isotope analysis to assess natural versus Fe(0) barrier-induced degradation of chlorinated ethenes at a contaminated site
Compound-specific isotopic analysis of multiple elements (C, Cl, H) was tested to better assess the effect of a zero-valent iron-permeable reactive barrier (ZVI-PRB) installation at a site contaminated with tetrachloroethene (PCE) and trichloroethene (TCE). The focus was on (1) using 13C to evaluate...
| Autores: | , , , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/155353 |
| Acceso en línea: | https://hdl.handle.net/2445/155353 |
| Access Level: | acceso abierto |
| Palabra clave: | Contaminació de l'aigua Depuració d'aigües residuals Hidrologia d'aigües subterrànies Isòtops Water pollution Purification of sewage Groundwater hydrology Isotopes |
| Sumario: | Compound-specific isotopic analysis of multiple elements (C, Cl, H) was tested to better assess the effect of a zero-valent iron-permeable reactive barrier (ZVI-PRB) installation at a site contaminated with tetrachloroethene (PCE) and trichloroethene (TCE). The focus was on (1) using 13C to evaluate natural chlorinated ethene biodegradation and the ZVI-PRB efficiency; (2) using dual element 13C-37Cl isotopic analysis to distinguish biotic from abiotic degradation of cis-dichloroethene (cis-DCE); and (3) using 13C-37Cl-2H isotopic analysis of cis-DCE and TCE to elucidate different contaminant sources. Both biodegradation and degradation by ZVI-PRB were indicated by the metabolites that were detected and the 13C data, with a quantitative estimate of the ZVI-PRB efficiency of less than 10% for PCE. Dual ele- ment 13C-37Cl isotopic plots confirmed that biodegradation was the main process at the site including the ZVI-PRB area. Based on the carbon isotope data, approximately 45% and 71% of PCE and TCE, respec- tively, were estimated to be removed by biodegradation. 2H combined with 13C and 37Cl seems to have identified two discrete sources contributing to the contaminant plume, indicating the potential of 2 H to discriminate whether a compound is of industrial origin, or whether a compound is formed as a daughter product during degradation. |
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