Thermal conductivity of MoS2 polycrystalline nanomembranes

Heat conduction in 2D materials can be effectively engineered by means of controlling nanoscale grain structure. Afavorable thermal performance makes these structures excellent candidates for integrated heat management units. Here we show combined experimental and theoretical studies for MoS₂ nanosh...

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Detalles Bibliográficos
Autores: Sledzinska, Marianna|||0000-0001-8592-1121, Graczykowski, Bartlomiej|||0000-0003-4787-8622, Placidi, Marcel, Saleta Reig, David|||0000-0003-3189-2331, Sachat, Alexandros el|||0000-0003-3798-9724, Reparaz, Juan Sebastián|||0000-0001-9679-0075, Alzina, Francesc|||0000-0002-7082-0624, Mortazavi, Bohayra|||0000-0003-3031-5057, Quey, Romain|||0000-0002-1593-8179, Colombo, Luciano|||0000-0001-5335-4652, Roche, Stephan|||0000-0003-0323-4665, Sotomayor Torres, Clivia M.|||0000-0001-9986-2716
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:200182
Acceso en línea:https://ddd.uab.cat/record/200182
https://dx.doi.org/urn:doi:10.1088/2053-1583/3/3/035016
Access Level:acceso abierto
Palabra clave:Nanoscale thermal transport
Thermal conductivity
Ultra-thin membranes
Descripción
Sumario:Heat conduction in 2D materials can be effectively engineered by means of controlling nanoscale grain structure. Afavorable thermal performance makes these structures excellent candidates for integrated heat management units. Here we show combined experimental and theoretical studies for MoS₂ nanosheets in a nanoscale grain-size limit.Wereport thermal conductivity measurements on 5 nm thick polycrystalline MoS₂ by means of 2-laser Raman thermometry. The free-standing, drum-like MoS₂ nanomembranes were fabricated using a novel polymer- and residue-free, wet transfer, in which we took advantage of the difference in the surface energies between MoS₂ and the growth substrate to transfer the CVD-grown nanosheets. The measurements revealed a strong reduction in the in-plane thermal conductivity down to about 0.73 ± 0.25 W m⁻¹ K⁻¹. The results are discussed theoretically using finite elements method simulations for a polycrystalline film, and a scaling trend of the thermally conductivity with grain size is proposed.