A survey of recent synthetic applications of 2,3-dideoxy-hex-2-enopyranosides

Unsaturated carbohydrate derivatives are useful intermediates in synthetic transformations leading to a variety of compounds. The aim of this review is to highlight the rich chemistry of Δ-2,3 unsaturated pyranosides, emphasizing the variety of transformations that have been carried out in these sub...

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Detalhes bibliográficos
Autores: Gómez, Ana M., Lobo, Fernando, Miranda, Silvia, López Pérez, J. Cristóbal
Formato: artículo
Fecha de publicación:2015
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/115847
Acesso em linha:http://hdl.handle.net/10261/115847
Access Level:acceso abierto
Palavra-chave:Osmylation
Epoxidation
Glycosylation
Ferrier rearrangement
De novo synthesis
Cycloaddition
Hex-2,3-enopyranosides
Descrição
Resumo:Unsaturated carbohydrate derivatives are useful intermediates in synthetic transformations leading to a variety of compounds. The aim of this review is to highlight the rich chemistry of Δ-2,3 unsaturated pyranosides, emphasizing the variety of transformations that have been carried out in these substrates during the last decade.