Recent advances in the chemistry of group 9—Pincer organometallics

Tridentate pincer ligands can be tailored to perform functions beyond stereoelectronic influence. This chapter showcases such functions and analyzes their impact in the recent chemistry of group 9 coordination compounds. Hemilabile ligands, redox-active designs, and scaffolds equipped with lone elec...

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Detalhes bibliográficos
Autores: Martín, M., Sola, E.
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Recursos:Universidad de Zaragoza
Repositorio:Zaguán. Repositorio Digital de la Universidad de Zaragoza
OAI Identifier:oai:zaguan.unizar.es:149134
Acesso em linha:http://zaguan.unizar.es/record/149134
Access Level:acceso abierto
Descrição
Resumo:Tridentate pincer ligands can be tailored to perform functions beyond stereoelectronic influence. This chapter showcases such functions and analyzes their impact in the recent chemistry of group 9 coordination compounds. Hemilabile ligands, redox-active designs, and scaffolds equipped with lone electron pairs or protic groups are described, and their cooperation with metal centers is analyzed. Discussions never lose sight of the different reactivity of cobalt that results from its frequent one-electron chemistry.

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