Hg2+ optical fiber sensor based on LSPR generated by gold nanoparticles embedded in LBL nano-assembled coatings

Mercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanopart...

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Detalles Bibliográficos
Autores: Martínez Hernández, María Elena, Goicoechea Fernández, Javier, Arregui San Martín, Francisco Javier
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Universidad Pública de Navarra
Repositorio:Academica-e. Repositorio Institucional de la Universidad Pública de Navarra
OAI Identifier:oai:academica-e.unavarra.es:2454/36918
Acceso en línea:https://hdl.handle.net/2454/36918
Access Level:acceso abierto
Palabra clave:Fiber optic sensor
Gold nanoparticles
Localized surface plasmon resonance
Mercury
Ppb
Descripción
Sumario:Mercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanoparticles (AuNPs). The gold nanoparticles were obtained via a water-based synthesis route that use poly acrylic acid (PAA) as stabilizing agent, in the presence of a borane dimethylamine complex (DMAB) as reducing agent, giving PAA-capped AuNPs. The sensing mechanism is based on the alteration of the Localized Surface Plasmon Resonances (LSPR) generated by AuNPs thanks to the strong chemical affinity of metallic mercury towards gold, which lead to amalgam alloys.