Tuning the charge stabilization and transport in naphthalimide-based semiconductors via fused-ring and core-engineering strategy
The synthesis and characterization of a family of rationally designed compounds based on naphthalimide units attached, through conjugated nitrogenated linkers (i.e. pyrazine and imidazoline units), to fused thiophene-based moieties is shown. This combination of different donor-acceptor moieties allo...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/123878 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/123878 |
| Access Level: | acceso abierto |
| Palabra clave: | 547 Naphthalimide Charge transport thiophene Química orgánica (Química) 2306 Química Orgánica |
| Sumario: | The synthesis and characterization of a family of rationally designed compounds based on naphthalimide units attached, through conjugated nitrogenated linkers (i.e. pyrazine and imidazoline units), to fused thiophene-based moieties is shown. This combination of different donor-acceptor moieties allows fine tuning of the HOMO and LUMO energy levels, and thus the modulation of their electronic properties. A comprehensive physical chemistry study is approached here, in which the nature of the neutral and charged species are analyzed and their electrical performance is understood in terms of molecular and supramolecular characteristics. |
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