Quantifying Po-210/Pb-210 Disequilibrium in Seawater

The disequilibrium between lead-210 (Pb-210) and polonium-210 (Po-210) is increasingly used in oceanography to quantify particulate organic carbon (POC) export from the upper ocean. This proxy is based on the deficits of Po-210 typically observed in the upper water column due to the preferential rem...

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Detalles Bibliográficos
Autores: Roca-Martí, Montserrat|||0000-0002-4719-9358, Puigcorbé, Viena|||0000-0001-5892-2305, Castrillejo, Maxi|||0000-0001-5149-2218, Casacuberta Arola, Núria|||0000-0001-7316-1655, García Orellana, Jordi|||0000-0002-0543-2641, Cochran, J. Kirk, Masqué Barri, Pere|||0000-0002-1789-320X
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:307049
Acceso en línea:https://ddd.uab.cat/record/307049
https://dx.doi.org/urn:doi:10.3389/fmars.2021.684484
Access Level:acceso abierto
Palabra clave:Po/Pb disequilibrium
Co-APDC
Fe(OH)
Marine chemistry
Particle export
Polonium isotopes
Precipitation methods
Radiochemistry
Descripción
Sumario:The disequilibrium between lead-210 (Pb-210) and polonium-210 (Po-210) is increasingly used in oceanography to quantify particulate organic carbon (POC) export from the upper ocean. This proxy is based on the deficits of Po-210 typically observed in the upper water column due to the preferential removal of Po-210 relative to (21)0Pb by sinking particles. Yet, a number of studies have reported unexpected large Po-210 deficits in the deep ocean indicating scavenging of Po-210 despite its radioactive mean life of similar to 200 days. Two precipitation methods, Fe(OH)(3) and Co-APDC, are typically used to concentrate Pb and Po from seawater samples, and deep Po-210 deficits raise the question whether this feature is biogeochemically consistent or there is a methodological issue. Here, we present a compilation of Pb-210 and Po-210 studies that suggests that Po-210 deficits at depths.