Enyne ring-closing metathesis on heteroaromatic cations

Cationic heteroaromatic enynes have been employed as substrates in enyne ring-closing metathesis, under an atmosphere of ethylene and using the Hoveyda-Grubbs catalyst, for the first time; the reaction affords new 1-vinyl- and 2-vinyl-substituted 3,4-dihydroquinolizinium salts, useful precursors for...

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Autores: Núñez Ventura, Araceli, Cuadro Palacios, Ana María|||0000-0002-8077-6938, Álvarez-Builla Gómez, Julio, Vaquero López, Juan José|||0000-0002-3820-9673
Tipo de recurso: artículo
Fecha de publicación:2006
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/3215
Acceso en línea:http://hdl.handle.net/10017/3215
https://dx.doi.org/10.1039/b602420c
Access Level:acceso abierto
Palabra clave:1 Vinyl 3,4 dihydroquinolizinium derivative
2 Vinyl 3,4 dihydroquinolizinium derivative
Berberine derivative
Cation
Coralyne
Dihydroquinoline derivative
Enyne derivative
Ethylene
Heteroaromatic cation
Unclassified drug
Article
Cation transport
Chemical structure
Product recovery
Ring closing metathesis
Structure activity relation
Structure analysis
Ciencia
Química orgánica
Science
Chemistry, organic
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repository_id_str
spelling Enyne ring-closing metathesis on heteroaromatic cationsNúñez Ventura, AraceliCuadro Palacios, Ana María|||0000-0002-8077-6938Álvarez-Builla Gómez, JulioVaquero López, Juan José|||0000-0002-3820-96731 Vinyl 3,4 dihydroquinolizinium derivative2 Vinyl 3,4 dihydroquinolizinium derivativeBerberine derivativeCationCoralyneDihydroquinoline derivativeEnyne derivativeEthyleneHeteroaromatic cationUnclassified drugArticleCation transportChemical structureProduct recoveryRing closing metathesisStructure activity relationStructure analysisCienciaQuímica orgánicaScienceChemistry, organicCationic heteroaromatic enynes have been employed as substrates in enyne ring-closing metathesis, under an atmosphere of ethylene and using the Hoveyda-Grubbs catalyst, for the first time; the reaction affords new 1-vinyl- and 2-vinyl-substituted 3,4-dihydroquinolizinium salts, useful precursors for biologically relevant cations based on the quinolinizium system.The authors acknowledge support for this work from the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica, Ministerio de Ciencia y Tecnología through project BQU2002-03578 and a grant from the Comunidad de Madrid (A. N.).Ministerio de Ciencia y TecnologíaRoyal Society of Chemistry20062006-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/3215https://dx.doi.org/10.1039/b602420creponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengMICYT Not available BQU2002-03578 NUEVOS CROMOFOROS CON PROPIEDADES INTERCALANTES DE ADN, AFINIDAD Y SELECTIVIDADopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/32152026-06-18T11:13:07Z
dc.title.none.fl_str_mv Enyne ring-closing metathesis on heteroaromatic cations
title Enyne ring-closing metathesis on heteroaromatic cations
spellingShingle Enyne ring-closing metathesis on heteroaromatic cations
Núñez Ventura, Araceli
1 Vinyl 3,4 dihydroquinolizinium derivative
2 Vinyl 3,4 dihydroquinolizinium derivative
Berberine derivative
Cation
Coralyne
Dihydroquinoline derivative
Enyne derivative
Ethylene
Heteroaromatic cation
Unclassified drug
Article
Cation transport
Chemical structure
Product recovery
Ring closing metathesis
Structure activity relation
Structure analysis
Ciencia
Química orgánica
Science
Chemistry, organic
title_short Enyne ring-closing metathesis on heteroaromatic cations
title_full Enyne ring-closing metathesis on heteroaromatic cations
title_fullStr Enyne ring-closing metathesis on heteroaromatic cations
title_full_unstemmed Enyne ring-closing metathesis on heteroaromatic cations
title_sort Enyne ring-closing metathesis on heteroaromatic cations
dc.creator.none.fl_str_mv Núñez Ventura, Araceli
Cuadro Palacios, Ana María|||0000-0002-8077-6938
Álvarez-Builla Gómez, Julio
Vaquero López, Juan José|||0000-0002-3820-9673
author Núñez Ventura, Araceli
author_facet Núñez Ventura, Araceli
Cuadro Palacios, Ana María|||0000-0002-8077-6938
Álvarez-Builla Gómez, Julio
Vaquero López, Juan José|||0000-0002-3820-9673
author_role author
author2 Cuadro Palacios, Ana María|||0000-0002-8077-6938
Álvarez-Builla Gómez, Julio
Vaquero López, Juan José|||0000-0002-3820-9673
author2_role author
author
author
dc.subject.none.fl_str_mv 1 Vinyl 3,4 dihydroquinolizinium derivative
2 Vinyl 3,4 dihydroquinolizinium derivative
Berberine derivative
Cation
Coralyne
Dihydroquinoline derivative
Enyne derivative
Ethylene
Heteroaromatic cation
Unclassified drug
Article
Cation transport
Chemical structure
Product recovery
Ring closing metathesis
Structure activity relation
Structure analysis
Ciencia
Química orgánica
Science
Chemistry, organic
topic 1 Vinyl 3,4 dihydroquinolizinium derivative
2 Vinyl 3,4 dihydroquinolizinium derivative
Berberine derivative
Cation
Coralyne
Dihydroquinoline derivative
Enyne derivative
Ethylene
Heteroaromatic cation
Unclassified drug
Article
Cation transport
Chemical structure
Product recovery
Ring closing metathesis
Structure activity relation
Structure analysis
Ciencia
Química orgánica
Science
Chemistry, organic
description Cationic heteroaromatic enynes have been employed as substrates in enyne ring-closing metathesis, under an atmosphere of ethylene and using the Hoveyda-Grubbs catalyst, for the first time; the reaction affords new 1-vinyl- and 2-vinyl-substituted 3,4-dihydroquinolizinium salts, useful precursors for biologically relevant cations based on the quinolinizium system.
publishDate 2006
dc.date.none.fl_str_mv 2006
2006-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/3215
https://dx.doi.org/10.1039/b602420c
url http://hdl.handle.net/10017/3215
https://dx.doi.org/10.1039/b602420c
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv MICYT Not available BQU2002-03578 NUEVOS CROMOFOROS CON PROPIEDADES INTERCALANTES DE ADN, AFINIDAD Y SELECTIVIDAD
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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