The rich reactivity of transition metal carbenes with alkynes

Transition metal carbenes are versatile intermediates that can mediate many reactions. Among the different reactions they can participate in, their reactions with alkynes are especially diverse. The present digest describes the different reaction pathways that can take place when a transition metal...

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Detalhes bibliográficos
Autores: Torres Antón, Òscar, Pla i Quintana, Anna
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/13147
Acesso em linha:http://hdl.handle.net/10256/13147
Access Level:acceso abierto
Palavra-chave:Alquins
Alkynes
Carbens
Carbenes (Methylene compounds)
Catalitzadors metàl·lics de transició
Transition metal catalysts
Reaccions químiques
Chemical reactions
Descrição
Resumo:Transition metal carbenes are versatile intermediates that can mediate many reactions. Among the different reactions they can participate in, their reactions with alkynes are especially diverse. The present digest describes the different reaction pathways that can take place when a transition metal carbene reacts with an alkyne, summarizes the most recent developments for each reactivity profile, and tries to shed light on the factors influencing the different reaction types