Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries

This work focused on the evaluation of the kinetics of dyeing polyester fabrics with high molecular weight disperse dyes, at low temperature by solvent microemulsion. This study also compared the effect of two non-toxic agro-sourced auxiliaries (o-vanillin and coumarin) using a non-toxic organic sol...

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Autores: Radei, Shahram, Carrión-Fité, Francisco Javier, Ardanuy Raso, Mònica|||0000-0002-9809-2577, Canal Arias, José María|||0000-0001-7949-0177
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/114404
Acceso en línea:https://hdl.handle.net/2117/114404
https://dx.doi.org/10.3390/polym10020200
Access Level:acceso abierto
Palabra clave:Dyes and dyeing--Textile fibers, Synthetic
Textile fibers, Synthetic
Polyester fibers
Kinetics
Coumarins
Butyl acetate
Polyester dyeing
Microemulsion
O-vanillin
Coumarin
n-butyl acetate
Tints i tenyit -- Fibres tèxtils sintètiques
Fibres tèxtils sintètiques -- Tints i tenyit
Poliester
Cinètica química
Àrees temàtiques de la UPC::Enginyeria tèxtil::Fabricació tèxtil::Tintura
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network_acronym_str ES
network_name_str España
repository_id_str
spelling Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliariesRadei, ShahramCarrión-Fité, Francisco JavierArdanuy Raso, Mònica|||0000-0002-9809-2577Canal Arias, José María|||0000-0001-7949-0177Dyes and dyeing--Textile fibers, SyntheticTextile fibers, SyntheticPolyester fibersKineticsCoumarinsButyl acetatePolyester dyeingMicroemulsionO-vanillinCoumarinn-butyl acetateKineticsTints i tenyit -- Fibres tèxtils sintètiquesFibres tèxtils sintètiques -- Tints i tenyitPoliesterCinètica químicaÀrees temàtiques de la UPC::Enginyeria tèxtil::Fabricació tèxtil::TinturaThis work focused on the evaluation of the kinetics of dyeing polyester fabrics with high molecular weight disperse dyes, at low temperature by solvent microemulsion. This study also compared the effect of two non-toxic agro-sourced auxiliaries (o-vanillin and coumarin) using a non-toxic organic solvent. A dyeing bath consisting of a micro-emulsion system involving a small proportion of n-butyl acetate was used, and the kinetics of dyeing were analysed at four temperatures (83, 90, 95 and 100 °C). Moreover, the dyeing rate constants, correlation coefficient and activation energies were proposed for this system. It was found that o-vanillin yielded higher dye absorption levels than coumarin, leading to exhaustions of 88% and 87% for Disperse Red 167 and Disperse Blue 79, respectively. K/S values of dyed polyester were also found to be higher for dye baths containing o-vanillin with respect to the ones with coumarin. In terms of hot pressing fastness and wash fastness, generally no adverse influence on fastness properties was reported, while o-vanillin showed slightly better results compared to coumarin20182018-02-1620182018-02-23journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/114404https://dx.doi.org/10.3390/polym10020200reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution 3.0 Spainhttp://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/1144042026-05-27T15:37:01Z
dc.title.none.fl_str_mv Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
title Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
spellingShingle Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
Radei, Shahram
Dyes and dyeing--Textile fibers, Synthetic
Textile fibers, Synthetic
Polyester fibers
Kinetics
Coumarins
Butyl acetate
Polyester dyeing
Microemulsion
O-vanillin
Coumarin
n-butyl acetate
Kinetics
Tints i tenyit -- Fibres tèxtils sintètiques
Fibres tèxtils sintètiques -- Tints i tenyit
Poliester
Cinètica química
Àrees temàtiques de la UPC::Enginyeria tèxtil::Fabricació tèxtil::Tintura
title_short Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
title_full Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
title_fullStr Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
title_full_unstemmed Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
title_sort Kinetics of low temperature polyester dyeing with high molecular weight disperse dyes by solvent microemulsion and agrosourced auxiliaries
dc.creator.none.fl_str_mv Radei, Shahram
Carrión-Fité, Francisco Javier
Ardanuy Raso, Mònica|||0000-0002-9809-2577
Canal Arias, José María|||0000-0001-7949-0177
author Radei, Shahram
author_facet Radei, Shahram
Carrión-Fité, Francisco Javier
Ardanuy Raso, Mònica|||0000-0002-9809-2577
Canal Arias, José María|||0000-0001-7949-0177
author_role author
author2 Carrión-Fité, Francisco Javier
Ardanuy Raso, Mònica|||0000-0002-9809-2577
Canal Arias, José María|||0000-0001-7949-0177
author2_role author
author
author
dc.subject.none.fl_str_mv Dyes and dyeing--Textile fibers, Synthetic
Textile fibers, Synthetic
Polyester fibers
Kinetics
Coumarins
Butyl acetate
Polyester dyeing
Microemulsion
O-vanillin
Coumarin
n-butyl acetate
Kinetics
Tints i tenyit -- Fibres tèxtils sintètiques
Fibres tèxtils sintètiques -- Tints i tenyit
Poliester
Cinètica química
Àrees temàtiques de la UPC::Enginyeria tèxtil::Fabricació tèxtil::Tintura
topic Dyes and dyeing--Textile fibers, Synthetic
Textile fibers, Synthetic
Polyester fibers
Kinetics
Coumarins
Butyl acetate
Polyester dyeing
Microemulsion
O-vanillin
Coumarin
n-butyl acetate
Kinetics
Tints i tenyit -- Fibres tèxtils sintètiques
Fibres tèxtils sintètiques -- Tints i tenyit
Poliester
Cinètica química
Àrees temàtiques de la UPC::Enginyeria tèxtil::Fabricació tèxtil::Tintura
description This work focused on the evaluation of the kinetics of dyeing polyester fabrics with high molecular weight disperse dyes, at low temperature by solvent microemulsion. This study also compared the effect of two non-toxic agro-sourced auxiliaries (o-vanillin and coumarin) using a non-toxic organic solvent. A dyeing bath consisting of a micro-emulsion system involving a small proportion of n-butyl acetate was used, and the kinetics of dyeing were analysed at four temperatures (83, 90, 95 and 100 °C). Moreover, the dyeing rate constants, correlation coefficient and activation energies were proposed for this system. It was found that o-vanillin yielded higher dye absorption levels than coumarin, leading to exhaustions of 88% and 87% for Disperse Red 167 and Disperse Blue 79, respectively. K/S values of dyed polyester were also found to be higher for dye baths containing o-vanillin with respect to the ones with coumarin. In terms of hot pressing fastness and wash fastness, generally no adverse influence on fastness properties was reported, while o-vanillin showed slightly better results compared to coumarin
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-02-16
2018
2018-02-23
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/114404
https://dx.doi.org/10.3390/polym10020200
url https://hdl.handle.net/2117/114404
https://dx.doi.org/10.3390/polym10020200
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 3.0 Spain
http://creativecommons.org/licenses/by/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 3.0 Spain
http://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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