A Mn6 cluster inside a Mn10 wheel: characterization of a Mn16-oximate complex and the new tetrazole-2-pyridilketoneokimate ligand
A new Mn16 topology consisting of one hexanuclear {MnII2MnIII4} unit coordinated inside a decametallic {MnII6MnIII2MnIV 2} wheel was synthesized from 2-pyridyl-cyanoxime and azido ligands. A new tetrazole-2-pyridylketoneoximate ligand was obtained in situ by cyclization of the cyano group and azide...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/164598 |
| Acceso en línea: | https://hdl.handle.net/2445/164598 |
| Access Level: | acceso abierto |
| Palabra clave: | Manganès Propietats magnètiques Manganese Magnetic properties |
| Sumario: | A new Mn16 topology consisting of one hexanuclear {MnII2MnIII4} unit coordinated inside a decametallic {MnII6MnIII2MnIV 2} wheel was synthesized from 2-pyridyl-cyanoxime and azido ligands. A new tetrazole-2-pyridylketoneoximate ligand was obtained in situ by cyclization of the cyano group and azide mediated by manganese cations. |
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