Applicability of a Supported Liquid Membrane in the Enrichment and Determination of Cadmium from Complex Aqueous Samples

A supported liquid membrane is developed for the separation of Cd from either high in salinity or acidity aqueous media. The membrane consisted of a durapore (polyvinylidene difluoride) polymeric support impregnated with a 0.5 M Aliquat 336 solution in decaline. The effect of carrier concentration,...

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Detalhes bibliográficos
Autores: Pont, Núria, Salvadó Martín, Victòria, Fontàs Rigau, Clàudia
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2018
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/15444
Acesso em linha:http://hdl.handle.net/10256/15444
Access Level:Acceso aberto
Palavra-chave:Membranes (Tecnologia)
Membranes (Technology)
Membranes lipídiques
Lipid membranes
Separació (Tecnologia)
Separation (Technology)
Descrição
Resumo:A supported liquid membrane is developed for the separation of Cd from either high in salinity or acidity aqueous media. The membrane consisted of a durapore (polyvinylidene difluoride) polymeric support impregnated with a 0.5 M Aliquat 336 solution in decaline. The effect of carrier concentration, organic solvent and feed and receiving solutions on the metal permeability is studied. This system allows the effective transport of trace levels of Cd through the formation of CdCl42−, which is the predominant species responsible for the extraction process, in both NaCl and HCl solutions. The supported liquid membrane system in a hollow fibre configuration allows the enrichment and separation of trace levels of Cd from spiked seawater samples, facilitating the analytical determination of this toxic metal